Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids
文献类型：期刊论文
| 作者 | Wu L(吴丽)1,2 ; Li Z(李臻)1; Wang F(王芳)1; Lei M(雷敏)1,2; Chen J(陈静)1; Li Z(李臻)
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| 刊名 | Journal of Molecular Catalysis A: Chemical
 |
| 出版日期 | 2013 |
| 卷号 | 379页码:86-93 |
| 关键词 | Bronsted acidic ionic liquids Cyclotrimerization Kinetics study Quantum chemistry calculations |
| ISSN号 | 1381-1169 |
| 通讯作者 | 李臻 |
| 英文摘要 | Several Brönsted acidic ionic liquids (BAILs) were synthesized and used as catalysts for the cyclotrimeriza-tion of propanal. The acidity of different BAILs was explored and a preliminarily study of the relationshipbetween catalytic activity and acidity was performed. The kinetics for the BAILs-catalyzed cyclotrimer-ization of propanal was studied systemically to determine the kinetic model and the kinetic parametersby taking [BSTMG][HSO4] as the representative catalyst. The effects of various parameters such as cat-alyst loading, reaction temperature on the kinetics were examined in detail. Besides, the structures ofthree representative BAILs and the interactions between propanal molecule and ionic pairs of BAILs werestudied by means of quantum chemistry calculations. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 21133011);National Basic Research Program of China (973 Program) (No. 2011CB201404) |
| 语种 | 英语 |
| WOS记录号 | WOS:000326772700013 |
| 公开日期 | 2013-12-02 |
| 源URL | [http://210.77.64.217/handle/362003/4254]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Li Z(李臻) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu L,Li Z,Wang F,et al. Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids[J]. Journal of Molecular Catalysis A: Chemical,2013,379:86-93. |
| APA | Wu L,Li Z,Wang F,Lei M,Chen J,&李臻.(2013).Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids.Journal of Molecular Catalysis A: Chemical,379,86-93. |
| MLA | Wu L,et al."Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids".Journal of Molecular Catalysis A: Chemical 379(2013):86-93. |
入库方式： OAI收割
来源：兰州化学物理研究所
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