Tuning the Tribological Property with Thermal Sensitive Microgels for Aqueous Lubrication
文献类型：期刊论文
| 作者 | Liu GQ(刘国强)1,2 ; Wang XL(王晓龙)1; Zhou F(周峰)1; Liu WM(刘维民)1; Liu WM(刘维民); Zhou F(周峰)
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| 刊名 | ACS Applied Materials & Interfaces
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| 出版日期 | 2013 |
| 卷号 | 5期号:21页码:10842-10852 |
| 关键词 | tribology thermoresponsive microgels hydration lubrication soft matter |
| ISSN号 | 1944-8244 |
| 通讯作者 | 周峰 ; 刘维民 |
| 英文摘要 | Thermoresponsive microgels, poly(N-isopropylacrylamide)-graft-poly(ethylene glycol) (PNIPAAm-g-PEG), were synthesized via emulsifier-free emulsion polymerization and the tribological property as water lubricating additive was studied. The microgels had good thermoresponsive collapse/swelling performance with lower critical solution temperature (LCST) ca. 38.4 ℃. The rheological characterization and tribological tests showed that the microgels had a good lubricating performance in aqueous lubrication through interfacial physisorption and hydration lubrication, but the friction coefficient was impacted by temperature (below and above LCST). The tunable thermosensitive tribological property was attributed to the hydrophobic interaction and the enhanced interfacial absorption, which were both triggered by the elevated temperature. Furthermore, in order to avoid the water erosion in aqueous lubrication, the microgels were used together with 1H-benzotriazoles (BTA). Because of the good antifriction and anticorrosion property of BTA and the interplay between microgels and BTA, the microgels/BTA exhibited a synergistic effect in aqueous lubrication and the tribological property was more sensitive around the LCST. The present work is beneficial to understanding the tribological property of responsive microgels in aqueous lubrication and provides a novel approach for achieving low-friction through soft matters. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the NSFC (21125316;51171202);973 project (2013CB632300);Key Research Program of the Chinese Academy of Sciences (KJZDEW-M01) |
| 语种 | 英语 |
| WOS记录号 | WOS:000327103500057 |
| 公开日期 | 2013-12-02 |
| 源URL | [http://210.77.64.217/handle/362003/4265]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 通讯作者 | Liu WM(刘维民); Zhou F(周峰) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu GQ,Wang XL,Zhou F,et al. Tuning the Tribological Property with Thermal Sensitive Microgels for Aqueous Lubrication[J]. ACS Applied Materials & Interfaces,2013,5(21):10842-10852. |
| APA | Liu GQ,Wang XL,Zhou F,Liu WM,刘维民,&周峰.(2013).Tuning the Tribological Property with Thermal Sensitive Microgels for Aqueous Lubrication.ACS Applied Materials & Interfaces,5(21),10842-10852. |
| MLA | Liu GQ,et al."Tuning the Tribological Property with Thermal Sensitive Microgels for Aqueous Lubrication".ACS Applied Materials & Interfaces 5.21(2013):10842-10852. |
入库方式： OAI收割
来源：兰州化学物理研究所
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