Preparation of Cu2ZnSnS4 thin films by sulfurization of metallic precursors evaporated with a single source
文献类型:期刊论文
作者 | Jiang X(姜欣)1,2,3![]() ![]() |
刊名 | Surface and Coatings Technology
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出版日期 | 2013 |
卷号 | 228页码:S408-S411 |
关键词 | Cu2ZnSnS4 Thin film Solar cell Evaporation Sulfurization |
ISSN号 | 0257-8972 |
通讯作者 | 陈建敏 |
英文摘要 | In this study, Cu2ZnSnS4 (CZTS) thin films were prepared on Mo-coated soda-lime glass substrates by sulfurization of precursors deposited by single-source evaporating the metallic mixture of Cu-Zn-Sn. The influences of the composition ratio of evaporation sources and sulfurization temperature on the properties of CZTS thin films were investigated. The morphology, composition and structure of CZTS thin films were studied by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and Raman scattering, respectively. The XRD patterns revealed that CZTS films from both Cu-rich and Cu- correct evaporation sources contained a Cu-1.96 S phase, whereas films from Cu-poor evaporation sources showed no secondary phase and exhibited kesterite structure with a (112) plane preferred orientation. This identification was further confirmed by a Raman spectroscope. In addition, the results of XRD patterns and SEM images showed that the crystalline quality and surface morphology of CZTS thin films were greatly improved by increasing the sulfurization temperature. The CZTS thin films possessing a near-stoichiometric composition, homogeneous surface morphology and a single CZTS phase were fabricated using a Cu-poor evaporation source at the sulfurization temperature of 550 ℃, and it is suitable for CZTS based high performance solar cells as absorber. |
WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
学科主题 | 材料科学与物理化学 |
类目[WOS] | Materials Science, Coatings & Films ; Physics, Applied |
研究领域[WOS] | Materials Science ; Physics |
关键词[WOS] | PULSED-LASER DEPOSITION ; SOLAR-CELLS |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (Grant No. 50705093;No. 50575217);the Innovative Group Foundation from NSFC (Grant No. 50421502);the National 973 Project (No. 2007 CB607601) |
语种 | 英语 |
WOS记录号 | WOS:000323628400088 |
公开日期 | 2013-12-09 |
源URL | [http://210.77.64.217/handle/362003/4565] ![]() |
专题 | 兰州化学物理研究所_先进润滑与防护材料研究发展中心 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Zhanjiang Normal Univ, Sch Phys Sci & Technol, Zhanjiang 524048, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang X,Shao, Le-Xi,Zhang, Jun,et al. Preparation of Cu2ZnSnS4 thin films by sulfurization of metallic precursors evaporated with a single source[J]. Surface and Coatings Technology,2013,228:S408-S411. |
APA | Jiang X.,Shao, Le-Xi.,Zhang, Jun.,Li, Da.,Xie, Wei.,...&Chen JM.(2013).Preparation of Cu2ZnSnS4 thin films by sulfurization of metallic precursors evaporated with a single source.Surface and Coatings Technology,228,S408-S411. |
MLA | Jiang X,et al."Preparation of Cu2ZnSnS4 thin films by sulfurization of metallic precursors evaporated with a single source".Surface and Coatings Technology 228(2013):S408-S411. |
入库方式: OAI收割
来源:兰州化学物理研究所
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