Synthesis, characterization, and swelling behaviors of a pH-responsive CMC-g-poly(AA-co-AMPS) superabsorbent hydrogel
文献类型：期刊论文
| 作者 | Wang YZ(王益哲)1,2 ; Shi XN(施小宁)1,2; Wang WB(王文波)1; Wang AQ(王爱勤)1
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| 刊名 | Turkish Journal of Chemistry
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| 出版日期 | 2013 |
| 卷号 | 37期号:1页码:149-159 |
| 关键词 | Carboxymethyl cellulose acrylic acid 2-acrylamido-2-methylpropanesulfonic acid superabsorbent hydrogel pH-responsive |
| ISSN号 | 1300-0527 |
| 通讯作者 | 王爱勤 |
| 英文摘要 | New superabsorbent hydrogels were synthesized through free radical graft copolymerization of partially neutralized acrylic acid (AA) and 2-acrylamido-2-methylpropanesulfonic acid (AMPS) onto carboxymethyl cellulose (CMC) backbones. The structure and morphology of the synthesized superabsorbent hydrogels were characterized by Fourier transform infrared spectroscopy and scanning electron microscope. The effect of the molar ratio of AMPS to AA, the APS concentration, and the CMC content on swelling ratio was optimized. The swelling properties in various pH solutions and saline solutions as well as the swelling kinetics were also evaluated. Results showed that the introduction of AMPS enhanced the swelling capacity, swelling rate, and salt-resistance of the superabsorbent hydrogels. Moreover, the hydrogels exhibited smart swelling behavior in multivalent salt solutions and better reversible pH sensitivity in the pH 2.0 and 7.0 solutions, which makes the hydrogels available as a candidate for drug delivery systems. |
| 学科主题 | 功能复合材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 51003112);the Open Fund of the Key Laboratory of Chemistry of Northwestern Plant Resources, China Academy of Sciences (No. CNPR2010kfkt01) |
| 语种 | 英语 |
| WOS记录号 | WOS:000315619800011 |
| 公开日期 | 2013-12-05 |
| 源URL | [http://210.77.64.217/handle/362003/4529]  |
| 专题 | 兰州化学物理研究所_环境材料与生态化学研究发展中心 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang YZ,Shi XN,Wang WB,et al. Synthesis, characterization, and swelling behaviors of a pH-responsive CMC-g-poly(AA-co-AMPS) superabsorbent hydrogel[J]. Turkish Journal of Chemistry,2013,37(1):149-159. |
| APA | Wang YZ,Shi XN,Wang WB,&Wang AQ.(2013).Synthesis, characterization, and swelling behaviors of a pH-responsive CMC-g-poly(AA-co-AMPS) superabsorbent hydrogel.Turkish Journal of Chemistry,37(1),149-159. |
| MLA | Wang YZ,et al."Synthesis, characterization, and swelling behaviors of a pH-responsive CMC-g-poly(AA-co-AMPS) superabsorbent hydrogel".Turkish Journal of Chemistry 37.1(2013):149-159. |
入库方式： OAI收割
来源：兰州化学物理研究所
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