pH-responsive sodium alginate-based superporous hydrogel generated by an anionic surfactant micelle templating
文献类型:期刊论文
作者 | Shi XN(施小宁)1,2; Wang WB(王文波)1,3![]() ![]() |
刊名 | Carbohydrate Polymers
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出版日期 | 2013 |
卷号 | 94期号:1页码:449-455 |
关键词 | Superporous hydrogel SDS micelle templating Sodium alginate Morphology Swelling kinetics |
ISSN号 | 0144-8617 |
通讯作者 | 王爱勤 |
英文摘要 | A novel sodium alginate-based superporous hydrogel (SPH) was prepared by the grafting copolymeriza-tion and micelle templating formed by the self-assembled anionic surfactant sodium n-dodecyl sulfonate (SDS). Fourier transform infrared (FTIR) spectra demonstrated that SDS was removed from the final hydro-gel network. The formation mechanism of NaAlg-based SPH was proposed. Effect of SDS concentration on the morphologies and pore structure of the hydrogel was evaluated by Scanning Electron Microscopy (SEM), and the SDS-1.92 mM sample displays homogeneous and well-defined pores, which contribute to improve swelling ratio and swelling rate. The time-dependent swelling behaviors of the SDS-1.92 mM samples in various salt and pH solutions were investigated. The swelling in multivalent salt (Ca2+, Al3+)/pH 2 solutions displayed a well-known “overshooting effect”, whereas, its swelling kinetics in Na+/pH 3–12 solutions followed Schott’s pseudo second-order swelling kinetics model. |
学科主题 | 功能复合材料 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (No. 20877077);the Open Fund of the Key Laboratory of Chemistry of Northwestern Plant Resources, China Academy of Sciences (No. CNPR2010kfkt01) |
语种 | 英语 |
WOS记录号 | WOS:000317888500061 |
公开日期 | 2013-12-06 |
源URL | [http://210.77.64.217/handle/362003/4545] ![]() |
专题 | 兰州化学物理研究所_环境材料与生态化学研究发展中心 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, R&D Ctr Xuyi Attapulgite Appl Technol, Lanzhou 730000, Peoples R China 2.Gansu Univ Tradit Chinese Med, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Shi XN,Wang WB,Wang AQ. pH-responsive sodium alginate-based superporous hydrogel generated by an anionic surfactant micelle templating[J]. Carbohydrate Polymers,2013,94(1):449-455. |
APA | Shi XN,Wang WB,&Wang AQ.(2013).pH-responsive sodium alginate-based superporous hydrogel generated by an anionic surfactant micelle templating.Carbohydrate Polymers,94(1),449-455. |
MLA | Shi XN,et al."pH-responsive sodium alginate-based superporous hydrogel generated by an anionic surfactant micelle templating".Carbohydrate Polymers 94.1(2013):449-455. |
入库方式: OAI收割
来源:兰州化学物理研究所
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