Ferrous Centers Confined on Core-Shell Nanostructures for Low-Temperature CO Oxidation
文献类型：期刊论文
| 作者 | Guo, XG ; Fu, Q ; Ning, YX ; Wei, MM ; Li, MR ; Zhang, S（张硕） ; Jiang, Z（姜政） ; Bao, XH |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2012 |
| 卷号 | 134期号:30 |
| ISSN号 | 0002-7863 |
| 英文摘要 | A noble metal (NM) can stabilize monolayer-dispersed surface oxide phases with metastable nature. The formed "oxide-on-metal" inverse catalyst presents better catalytic performance than the NM because of the introduction of coordinatively unsaturated cations at the oxide-metal boundaries. Here we demonstrate that an ultrathin NM layer grown on a non-NM core can impose the same constraint on the supported oxide as the bulk NM. Cu@Pt core-shell nanoparticles (NPs) decorated with FeO patches use much less Pt but exhibit performance similar to that of Pt NPs covered with surface FeO patches in the catalytic oxidation of CO. The "oxide-on-core@shell" inverse catalyst system may open a new avenue for the design of advanced nanocatalysts with decreased usage of noble metals. |
| 语种 | 英语 |
| WOS记录号 | WOS:000306942600008 |
| 公开日期 | 2013-12-05 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/13167]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Guo, XG,Fu, Q,Ning, YX,et al. Ferrous Centers Confined on Core-Shell Nanostructures for Low-Temperature CO Oxidation[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2012,134(30). |
| APA | Guo, XG.,Fu, Q.,Ning, YX.,Wei, MM.,Li, MR.,...&Bao, XH.(2012).Ferrous Centers Confined on Core-Shell Nanostructures for Low-Temperature CO Oxidation.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,134(30). |
| MLA | Guo, XG,et al."Ferrous Centers Confined on Core-Shell Nanostructures for Low-Temperature CO Oxidation".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134.30(2012). |
入库方式： OAI收割
来源：上海应用物理研究所
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