Self-assembling subnanometer pores with unusual mass-transport properties
文献类型：期刊论文
| 作者 | Zhou, XB ; Liu, GD ; Yamato, K ; Shen, Y ; Cheng, RX ; Wei, XX ; Bai, WL ; Gao, Y ; Li, H ; Liu, Y ; Liu, FT ; Czajkowsky, DM ; Wang, JF ; Dabney, MJ ; Cai, ZH ; Hu, J(胡钧) ; Bright, FV ; He, L ; Zeng, XC ; Shao, ZF ; Gong, B |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2012 |
| 卷号 | 3 |
| ISSN号 | 2041-1723 |
| 英文摘要 | A long-standing aim in molecular self-assembly is the development of synthetic nanopores capable of mimicking the mass-transport characteristics of biological channels and pores. Here we report a strategy for enforcing the nanotubular assembly of rigid macrocycles in both the solid state and solution based on the interplay of multiple hydrogen-bonding and aromatic pi-pi stacking interactions. The resultant nanotubes have modifiable surfaces and inner pores of a uniform diameter defined by the constituent macrocycles. The self-assembling hydrophobic nanopores can mediate not only highly selective transmembrane ion transport, unprecedented for a synthetic nanopore, but also highly efficient transmembrane water permeability. These results establish a solid foundation for developing synthetically accessible, robust nanostructured systems with broad applications such as reconstituted mimicry of defined functions solely achieved by biological nanostructures, molecular sensing, and the fabrication of porous materials required for water purification and molecular separations. |
| 语种 | 英语 |
| WOS记录号 | WOS:000306995000021 |
| 公开日期 | 2013-12-05 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/13285]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhou, XB,Liu, GD,Yamato, K,et al. Self-assembling subnanometer pores with unusual mass-transport properties[J]. NATURE COMMUNICATIONS,2012,3. |
| APA | Zhou, XB.,Liu, GD.,Yamato, K.,Shen, Y.,Cheng, RX.,...&Gong, B.(2012).Self-assembling subnanometer pores with unusual mass-transport properties.NATURE COMMUNICATIONS,3. |
| MLA | Zhou, XB,et al."Self-assembling subnanometer pores with unusual mass-transport properties".NATURE COMMUNICATIONS 3(2012). |
入库方式： OAI收割
来源：上海应用物理研究所
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