Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity
文献类型:会议论文
作者 | Jiang H(姜恒)![]() ![]() ![]() ![]() |
出版日期 | 2013 |
会议名称 | 13th China Hydrogen Energy Conference (CHEC) / 5th Mainland, Taiwan and Hong Kong Symposium on Hydrogen Energy |
会议日期 | SEP 21-23, 2012 |
会议地点 | Nanjing, PEOPLES R CHINA |
通讯作者邮箱 | yurenwang@imech.ac.cn |
关键词 | Metal-organic frameworks Interpenetrated structure Hydrogen-storage Multi-walled carbon nanotubes High mesoporosity |
卷号 | 38 |
期号 | 25 |
页码 | 10950-10955 |
通讯作者 | Wang, YR (reprint author), Chinese Acad Sci, Inst Mech, Key Lab Micrograv, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China. |
中文摘要 | Metal-organic frameworks (MOFs) exhibiting high surface area and tunable pore size own broad application prospects. Compared with existing MOFs, MOF-5 [Zn4O(bdc)(3)] is a promising hydrogen storage material due to high H-2 uptake capacity and thermostability. However, further wider applications of MOF-5 have been limited because atmospheric moisture levels cause MOF-5 instability. MOF-5 and multi-walled carbon nanotubes (MWCNTs) hybrid composite (denoted MOFMC) can enhance stability toward ambient moisture and improve hydrogen storage capacity. In this paper, the MOFMC, which has an interpenetrated structure with high mesoporosity, was synthesized. The MOFMC is denoted as Int-MOFMC-meso. It stored 2.02 wt% H-2 at 77 K under 1 bar, which is higher than the MOF-5 with similar structure and the earlier reported MOFMC material. Moreover, the Int-MOFMC-meso can also show more excellent performance of thermostability and moisture stability than the MOF-5 with similar structure. |
收录类别 | SCI ; EI |
产权排序 | [Jiang, Heng; Feng, Yafei; Chen, Meng; Wang, Yuren] Chinese Acad Sci, Inst Mech, Key Lab Micrograv, Beijing 100190, Peoples R China |
会议网址 | http://dx.doi.org/10.1016/j.ijhydene.2013.03.044 |
会议录 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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会议录出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
学科主题 | Chemistry ; Physical; Electrochemistry; Energy & Fuels |
分类号 | 二类/Q2 |
语种 | 英语 |
ISSN号 | 0360-3199 |
源URL | [http://dspace.imech.ac.cn/handle/311007/47569] ![]() |
专题 | 力学研究所_国家微重力实验室 |
推荐引用方式 GB/T 7714 | Jiang H,Feng YF,Chen M,et al. Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity[C]. 见:13th China Hydrogen Energy Conference (CHEC) / 5th Mainland, Taiwan and Hong Kong Symposium on Hydrogen Energy. Nanjing, PEOPLES R CHINA. SEP 21-23, 2012.http://dx.doi.org/10.1016/j.ijhydene.2013.03.044. |
入库方式: OAI收割
来源:力学研究所
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