Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes
文献类型：期刊论文
| 作者 | Zhao YX(赵艳霞)1,3; Lei YB(雷一波)2; Dong QS(董青松)1,3; Wu B(吴彪)2; Yang XJ(杨晓娟)1,2
|
| 刊名 | Chemistry - A European Journal
 |
| 出版日期 | 2013 |
| 卷号 | 19期号:36页码:12059-12066 |
| 关键词 | alkenes aluminum cycloaddition insertion reaction mechanisms |
| ISSN号 | 0947-6539 |
| 通讯作者 | 杨晓娟 |
| 英文摘要 | The reactions of dialumane [L(thf)Al-Al (thf)L] (1, L=[{(2,6- iPr2C6H3)NC(Me)}2]2_) with stilbene and styrene afforded the oxidation/insertion products [L(thf)Al(CH(Ph)-CH(Ph))AlL] (2) and [L(thf)Al(CH(Ph)-CH2)Al(thf)L] (3), respectively. In the presence of Na metal, precursor 1 reacted with butadienes, possibly through the reduced “dialumene” or the “carbene-like” :AlL species, to yield aluminacyclopentenes [LAl(CH2C(Me)=C(Me)CH2)Na]n (4a) and [Na(dme)3][LAl(CH2C(Me)=CHCH2)] (4b, dme=dimethoxyethane) as [1+4] cycloaddition products, as well as the [2+4] cycloaddition product 1,6-dialumina-3,8-cyclodecadiene, [{Na-(dme)}2][LAl(CH2C(Me)=C(Me)-CH2)2AlL] (5). The possible mechanisms of the cycloaddition reactions were studied by using DFT computations. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (20972169;21273170) |
| 语种 | 英语 |
| WOS记录号 | WOS:000323514600035 |
| 公开日期 | 2013-12-16 |
| 源URL | [http://210.77.64.217/handle/362003/4719]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao YX,Lei YB,Dong QS,et al. Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes[J]. Chemistry - A European Journal,2013,19(36):12059-12066. |
| APA | Zhao YX,Lei YB,Dong QS,Wu B,&Yang XJ.(2013).Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes.Chemistry - A European Journal,19(36),12059-12066. |
| MLA | Zhao YX,et al."Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes".Chemistry - A European Journal 19.36(2013):12059-12066. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。