From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand
文献类型:期刊论文
作者 | Wang JM(王佳敏)1,4![]() ![]() ![]() ![]() |
刊名 | CrystEngComm
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出版日期 | 2013 |
卷号 | 15期号:22页码:4540-4548 |
ISSN号 | 1466-8033 |
通讯作者 | 吴彪 |
英文摘要 | A 1,5-naphthylene-bridged bis-bisurea receptor (L) has been designed and its coordination behavior with various anions has been examined in the solid state and in solution. This rigid "bis-bidentate" ligand can act as a linker to afford one-dimensional anion coordination polymers (ACPs) and dinuclear complexes with a wide range of anions. In the ACPs, the anions occupy the nodes and the polymeric structure is held solely by the coordination (hydrogen bonds) of the ligand to the anion. The sulfate ion forms three different complexes with L, two of which are discrete 1 : 2 (host-guest) anion complexes and the third is an ACP. The complexes of acetate and terephthalate are also 1D ACPs. On the other hand, benzoate, chloride and bromide ions form dinuclear complexes with L. Solution binding studies of L toward the anions were carried out by H-1 NMR, UV-vis and fluorescence titrations, from which the binding stoichiometry and stability constants were obtained. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (Grant No. 21271149) |
语种 | 英语 |
WOS记录号 | WOS:000318944800017 |
公开日期 | 2013-12-16 |
源URL | [http://210.77.64.217/handle/362003/4721] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710069, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang JM,Li SG,Yang PJ,et al. From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand[J]. CrystEngComm,2013,15(22):4540-4548. |
APA | Wang JM,Li SG,Yang PJ,Huang XJ,Yang XJ,&Wu B.(2013).From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand.CrystEngComm,15(22),4540-4548. |
MLA | Wang JM,et al."From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand".CrystEngComm 15.22(2013):4540-4548. |
入库方式: OAI收割
来源:兰州化学物理研究所
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