中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand

文献类型:期刊论文

作者Wang JM(王佳敏)1,4; Li SG(李少光)1; Yang PJ(杨培菊)1; Huang XJ(黄晓卷)1; Yang XJ(杨晓娟)1; Wu B(吴彪)2,3
刊名CrystEngComm
出版日期2013
卷号15期号:22页码:4540-4548
ISSN号1466-8033
通讯作者吴彪
英文摘要A 1,5-naphthylene-bridged bis-bisurea receptor (L) has been designed and its coordination behavior with various anions has been examined in the solid state and in solution. This rigid "bis-bidentate" ligand can act as a linker to afford one-dimensional anion coordination polymers (ACPs) and dinuclear complexes with a wide range of anions. In the ACPs, the anions occupy the nodes and the polymeric structure is held solely by the coordination (hydrogen bonds) of the ligand to the anion. The sulfate ion forms three different complexes with L, two of which are discrete 1 : 2 (host-guest) anion complexes and the third is an ACP. The complexes of acetate and terephthalate are also 1D ACPs. On the other hand, benzoate, chloride and bromide ions form dinuclear complexes with L. Solution binding studies of L toward the anions were carried out by H-1 NMR, UV-vis and fluorescence titrations, from which the binding stoichiometry and stability constants were obtained.
学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (Grant No. 21271149)
语种英语
WOS记录号WOS:000318944800017
公开日期2013-12-16
源URL[http://210.77.64.217/handle/362003/4721]  
专题兰州化学物理研究所_OSSO国家重点实验室
兰州化学物理研究所_ERC国家工程研究中心
作者单位1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
2.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710069, Peoples R China
3.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
4.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wang JM,Li SG,Yang PJ,et al. From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand[J]. CrystEngComm,2013,15(22):4540-4548.
APA Wang JM,Li SG,Yang PJ,Huang XJ,Yang XJ,&Wu B.(2013).From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand.CrystEngComm,15(22),4540-4548.
MLA Wang JM,et al."From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand".CrystEngComm 15.22(2013):4540-4548.

入库方式: OAI收割

来源:兰州化学物理研究所

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