中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Merging the ring opening of benzoxazoles with secondary amines and an iron-catalyzed oxidative cyclization towards the environmentally friendly synthesis of 2-aminobenzoxazoles

文献类型:期刊论文

作者Xu DQ(徐大乾); Wang, Wenfang; Miao CX(苗成霞); Zhang QH(张巧红); Xia CG(夏春谷); Sun W(孙伟)
刊名Green Chemistry
出版日期2013
卷号15期号:10页码:2975-2980
ISSN号1463-9262
通讯作者孙伟
英文摘要A facile and environmentally friendly method was developed through merging the ring opening of benzoxazoles with secondary amines and an iron-catalyzed oxidative cyclization towards the synthesis of 2-aminobenzoxazoles. In the oxidative cyclization step, with catalytic amounts of FeCl and aqueous H2O2 as a green oxidant, highly desirable 2-aminobenzoxazoles were isolated in excellent yields of up to 97%. A plausible radical process is proposed for the oxidative cyclization on the basis of mechanistic studies.
收录类别SCI
资助信息the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21103207;21103206)
语种英语
WOS记录号WOS:000325593600043
公开日期2013-12-18
源URL[http://210.77.64.217/handle/362003/4763]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Xu DQ,Wang, Wenfang,Miao CX,et al. Merging the ring opening of benzoxazoles with secondary amines and an iron-catalyzed oxidative cyclization towards the environmentally friendly synthesis of 2-aminobenzoxazoles[J]. Green Chemistry,2013,15(10):2975-2980.
APA Xu DQ,Wang, Wenfang,Miao CX,Zhang QH,Xia CG,&Sun W.(2013).Merging the ring opening of benzoxazoles with secondary amines and an iron-catalyzed oxidative cyclization towards the environmentally friendly synthesis of 2-aminobenzoxazoles.Green Chemistry,15(10),2975-2980.
MLA Xu DQ,et al."Merging the ring opening of benzoxazoles with secondary amines and an iron-catalyzed oxidative cyclization towards the environmentally friendly synthesis of 2-aminobenzoxazoles".Green Chemistry 15.10(2013):2975-2980.

入库方式: OAI收割

来源:兰州化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。