Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins
文献类型：期刊论文
| 作者 | Wang XE(王晓娥)1,2; Miao CX(苗成霞)1 ; Wang SF(王寿峰)1; Xia CG(夏春谷)1; Sun W(孙伟)1
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| 刊名 | ChemCatChem
 |
| 出版日期 | 2013 |
| 卷号 | 5期号:8页码:2489-2494 |
| 关键词 | asymmetric epoxidation iron manganese N(4)ligand olefin |
| ISSN号 | 1867-3880 |
| 通讯作者 | 孙伟 |
| 英文摘要 | The manganese and iron complexes with the tetradentate N ligand (1R,2R)-N,N'-dimethyl-N,N'-bis(1-methyl-2-benzimidazolylmethyl)cyclohexane-1,2-diamine have been synthesized and characterized. cis- configuration. Both the manganese and iron complexes are active catalysts for the asymmetric epoxidation of olefins with H2O2 as an oxidant and acetic acid as an additive. Up to 96% ee was observed for the epoxidation of α,β-unsaturated ketones at -20 ℃. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21073210) |
| 语种 | 英语 |
| WOS记录号 | WOS:000322240600057 |
| 公开日期 | 2013-12-18 |
| 源URL | [http://210.77.64.217/handle/362003/4765]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang XE,Miao CX,Wang SF,et al. Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins[J]. ChemCatChem,2013,5(8):2489-2494. |
| APA | Wang XE,Miao CX,Wang SF,Xia CG,&Sun W.(2013).Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins.ChemCatChem,5(8),2489-2494. |
| MLA | Wang XE,et al."Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins".ChemCatChem 5.8(2013):2489-2494. |
入库方式： OAI收割
来源：兰州化学物理研究所
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