Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols
文献类型：期刊论文
| 作者 | Xie YJ(谢银君); Hu JH(胡建华); Jie P(解攀) ; Qian B(钱波); Huang HM(黄汉民)
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| 刊名 | Journal of the American Chemical Society
 |
| 出版日期 | 2013 |
| 卷号 | 135期号:49页码:18327-18330 |
| ISSN号 | 0002-7863 |
| 通讯作者 | 黄汉民 |
| 英文摘要 | A new strategy was developed for intercepting the palladium alkyl species generated in Heck reaction via nucleophilic addition prior to the step of migratory insertion, which leads to a new palladium-catalyzed difunctionalization of enol ethers with aminals and alcohols to afford amino acetals. Mechanistic studies suggested that the cationic cyclometalated Pd(II) complex generated by the oxidative addition of aminal to a Pd(0) species was crucial for this unusual transformation. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21172226;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000328438700022 |
| 公开日期 | 2013-12-18 |
| 源URL | [http://210.77.64.217/handle/362003/4781]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie YJ,Hu JH,Jie P,et al. Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols[J]. Journal of the American Chemical Society,2013,135(49):18327-18330. |
| APA | Xie YJ,Hu JH,Jie P,Qian B,&Huang HM.(2013).Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols.Journal of the American Chemical Society,135(49),18327-18330. |
| MLA | Xie YJ,et al."Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols".Journal of the American Chemical Society 135.49(2013):18327-18330. |
入库方式： OAI收割
来源：兰州化学物理研究所
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