Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion
文献类型：期刊论文
| 作者 | Li B(李斌)1 ; Yu B(于波)1; Huck, Wilhelm T. S.2; Liu WM(刘维民)1; Zhou F(周峰)1; Zhou F(周峰)
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| 刊名 | Journal of the American Chemical Society
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| 出版日期 | 2013 |
| 卷号 | 135期号:5页码:1708-1710 |
| ISSN号 | 0002-7863 |
| 通讯作者 | 周峰 |
| 英文摘要 | Surface initiated atom transfer radical polymerization (SI-ATRP) was triggered after diffusion of a Cu-I/L activator generated at a working electrode. A stable [(CuL)-L-II]/[(CuL)-L-I] ratio gradient was formed at the gap between the working electrode and the initiator terminated substrate due to ion diffusion. The size of the gap can be used to dictate polymer growth kinetics at different gap distances. Gradient polymer brushes were grafted when substrate was placed at a tilting angle along [(CuL)-L-II]/[(CuL)-L-I] gradient. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | NSFC (21125316;51171202);973 project (2013CB632300);the Key Research Program of the Chinese Academy of Sciences (grant no. KJZD-EW-M01) |
| 语种 | 英语 |
| WOS记录号 | WOS:000314794400019 |
| 公开日期 | 2013-12-12 |
| 源URL | [http://210.77.64.217/handle/362003/4676]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 通讯作者 | Zhou F(周峰) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands |
| 推荐引用方式 GB/T 7714 | Li B,Yu B,Huck, Wilhelm T. S.,et al. Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion[J]. Journal of the American Chemical Society,2013,135(5):1708-1710. |
| APA | Li B,Yu B,Huck, Wilhelm T. S.,Liu WM,Zhou F,&周峰.(2013).Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion.Journal of the American Chemical Society,135(5),1708-1710. |
| MLA | Li B,et al."Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion".Journal of the American Chemical Society 135.5(2013):1708-1710. |
入库方式： OAI收割
来源：兰州化学物理研究所
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