Low temperature synthesis of anatase and rutile titania nanopowders by hydrolysis of TiCl4 using ammonia gas
文献类型：期刊论文
| 作者 | Sun AH ; Guo PJ ; Li ZX ; Li Y ; Cui P |
| 刊名 | Journal of Alloys and Compounds
 |
| 出版日期 | 2009 |
| 期号 | 481页码:605–609 |
| 关键词 | Anatase Rutile Titania |
| 合作状况 | 国内 |
| 中文摘要 | A facile method is presented for preparing anatase and rutile titania nanopowders by hydrolysis of TiCl4 usingammoniagas asprecipitator at lowtemperatures (30–60℃). The influences of reaction temperature, pH value and aging time on the formation of titania nanopowders were systematically investigated. The prepared titania powders were characterized by X-ray diffraction (XRD), thermogravimetric (TG/DTA), scanning electron microscopy (SEM), transmission electron microscope (TEM), and dynamic light scattering (DLS). It was found that reaction temperature and pH values were the most influential factors in phase control of the nanopowders. Rutile phase titania was obtained at low temperature (30–60℃) if pH≤1. However, as pH≥4, the anatase phase was obtained in the same temperature range. Moreover, the aging time had no affect on the phase change of titania sample. Anatase converted completely to rutile phase after annealing at 700 ℃. Polyethylene glycol 1000 was used as a steric dispersant in this study, which made the product more uniform and spherical. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2010-01-05 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/211]  |
| 专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
| 推荐引用方式 GB/T 7714 | Sun AH,Guo PJ,Li ZX,et al. Low temperature synthesis of anatase and rutile titania nanopowders by hydrolysis of TiCl4 using ammonia gas[J]. Journal of Alloys and Compounds,2009(481):605–609. |
| APA | Sun AH,Guo PJ,Li ZX,Li Y,&Cui P.(2009).Low temperature synthesis of anatase and rutile titania nanopowders by hydrolysis of TiCl4 using ammonia gas.Journal of Alloys and Compounds(481),605–609. |
| MLA | Sun AH,et al."Low temperature synthesis of anatase and rutile titania nanopowders by hydrolysis of TiCl4 using ammonia gas".Journal of Alloys and Compounds .481(2009):605–609. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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