Preparation and Characterization of Poly(butylene terephthalate)/Silica Nanocomposites
文献类型:期刊论文
作者 | Yao XY ; Tian XY ; Zhang X ; Zheng K ; Zheng J ; Wang RX ; Kang SH ; Cui P |
刊名 | POLYMER ENGINEERING AND SCIENCE
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出版日期 | 2009 |
期号 | 49页码:799-807 |
合作状况 | 国内 |
中文摘要 | In this study, we presented a convenient, in situ polymerization route for the preparation of Poly (butylene terephthalate) (PBT)/silica nanocomposites, in which silica was not premodified. The nanocomposites were synthesized by in situ polymerization of terephthalic acid (TPA), 1,4-butanediol (BD) and silica. The structure of these nanocomposites were investigated by Fourier transform infrared (FTIR) and thermogravimetric analyses (TGA). The results show that PBT chains were successfully grafted onto the surface of silica. Transmission electron microscope (TEM) micrographs revealed that silica were homogeneously dispersed in PBT matrix at a size level of 10–20 nm. The isothermal crystallization kinetics of pure PBT and PBT/silica nanocomposites were investigated by differential scanning calorimeter (DSC) and simulated by Avrami model. The existence of silica could lead to an acceleration of crystallization and enhance the thermal stability of PBT. According to dynamic mechanical analysis (DMA), the storage modulus of PBT/silica nanocomposites were markedly improved compared with pure PBT. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2010-01-05 |
源URL | [http://ir.nimte.ac.cn/handle/174433/214] ![]() |
专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
推荐引用方式 GB/T 7714 | Yao XY,Tian XY,Zhang X,et al. Preparation and Characterization of Poly(butylene terephthalate)/Silica Nanocomposites[J]. POLYMER ENGINEERING AND SCIENCE,2009(49):799-807. |
APA | Yao XY.,Tian XY.,Zhang X.,Zheng K.,Zheng J.,...&Cui P.(2009).Preparation and Characterization of Poly(butylene terephthalate)/Silica Nanocomposites.POLYMER ENGINEERING AND SCIENCE(49),799-807. |
MLA | Yao XY,et al."Preparation and Characterization of Poly(butylene terephthalate)/Silica Nanocomposites".POLYMER ENGINEERING AND SCIENCE .49(2009):799-807. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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