中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films

文献类型:期刊论文

作者Sun XL ; Cao HT ; Liu ZM ; Li JZ
刊名Applied Surface Science
出版日期2009
期号255页码:8629–8633
关键词Electrochromic thin films Tungstic oxide Microstructure Optical properties
合作状况国内
中文摘要Tungsten oxide (WO3) thin films have been extensively studied for their interesting physical properties and a variety of potential applications in electrochromic devices. In order to explore the possibility of using these in electrochromic devices, a preliminary and thorough study of the optical properties of the host materials is an important step. Based on this, the influence of annealing temperature on the structural, surface morphological, optical and electrochromic properties has been investigated in the present work. The host material, WO3 films, has been prepared from an ethanolic acetylated peroxotungstic acid sol containing 5 wt.% oxalic acid dehydrate (OAD) by sol–gel technique. The monoclinic structure and textured nature change of the films with the temperature increasing have been investigated by X-ray diffraction analysis. The surface morphology evolution of the films has been characterized by SEM. The shift in absorption edge towards the higher wavelength region observed from optical studies may be due to the electron scattering effects and the optical band filling effect that reveals the crystallization of the film. The amorphous film shows better optical modulation (⊿T = 76.9% at λ= 610 nm), fast color-bleach kinetics (tc ~ 4 s and tb ~ 9 s) and good reversibility (Qb/Qc = 90%), thereby rendering it suitable for smart window applications.
收录类别SCI
语种英语
公开日期2010-01-06
源URL[http://ir.nimte.ac.cn/handle/174433/223]  
专题宁波材料技术与工程研究所_宁波所知识产出
推荐引用方式
GB/T 7714
Sun XL,Cao HT,Liu ZM,et al. Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films[J]. Applied Surface Science,2009(255):8629–8633.
APA Sun XL,Cao HT,Liu ZM,&Li JZ.(2009).Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films.Applied Surface Science(255),8629–8633.
MLA Sun XL,et al."Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films".Applied Surface Science .255(2009):8629–8633.

入库方式: OAI收割

来源:宁波材料技术与工程研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。