Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films
文献类型:期刊论文
作者 | Sun XL ; Cao HT ; Liu ZM ; Li JZ |
刊名 | Applied Surface Science
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出版日期 | 2009 |
期号 | 255页码:8629–8633 |
关键词 | Electrochromic thin films Tungstic oxide Microstructure Optical properties |
合作状况 | 国内 |
中文摘要 | Tungsten oxide (WO3) thin films have been extensively studied for their interesting physical properties and a variety of potential applications in electrochromic devices. In order to explore the possibility of using these in electrochromic devices, a preliminary and thorough study of the optical properties of the host materials is an important step. Based on this, the influence of annealing temperature on the structural, surface morphological, optical and electrochromic properties has been investigated in the present work. The host material, WO3 films, has been prepared from an ethanolic acetylated peroxotungstic acid sol containing 5 wt.% oxalic acid dehydrate (OAD) by sol–gel technique. The monoclinic structure and textured nature change of the films with the temperature increasing have been investigated by X-ray diffraction analysis. The surface morphology evolution of the films has been characterized by SEM. The shift in absorption edge towards the higher wavelength region observed from optical studies may be due to the electron scattering effects and the optical band filling effect that reveals the crystallization of the film. The amorphous film shows better optical modulation (⊿T = 76.9% at λ= 610 nm), fast color-bleach kinetics (tc ~ 4 s and tb ~ 9 s) and good reversibility (Qb/Qc = 90%), thereby rendering it suitable for smart window applications. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2010-01-06 |
源URL | [http://ir.nimte.ac.cn/handle/174433/223] ![]() |
专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
推荐引用方式 GB/T 7714 | Sun XL,Cao HT,Liu ZM,et al. Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films[J]. Applied Surface Science,2009(255):8629–8633. |
APA | Sun XL,Cao HT,Liu ZM,&Li JZ.(2009).Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films.Applied Surface Science(255),8629–8633. |
MLA | Sun XL,et al."Influence of annealing temperature on microstructure and optical properties of sol–gel derived tungsten oxide films".Applied Surface Science .255(2009):8629–8633. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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