Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(II) acetylacetonate
文献类型：期刊论文
| 作者 | Du J(杜娟) ; Baoru Bian,a Weixing Xia,a Juan Du,*a Jian Zhang,a J. Ping Liu,b Zhaohui Guoc and Aru Yana |
| 刊名 | Nanoscale.
 |
| 出版日期 | 2013-01-25 |
| 卷号 | 102期号:5页码:2454—2459 |
| 通讯作者 | 杜娟 |
| 合作状况 | 李雨桐 |
| 中文摘要 | By using Fe(CO)x -OAm (oleylamine, x< 5) as the Fe precursor to slow down the formation rate of FePt nanoparticles (NPs), a time dependence of the NPs' nucleation and growth process was observed by transmission electron microscopy (TEM). The complexing temperature of OAm and Fe(CO)5 at which Fe(CO)x-OAm was formed has a strong influence on the nucleation rate and growth process of the NPs. TEM analyses indicated that the NPs with isotropic shape were single crystalline throughout the synthesis and were formed by a diffusion-controlled Ostwald-ripening (OR) growth mechanism. The nanorod particles werefirst formedviajoining of arbitrarily oriented single crystals and the two crystals formed a uniform particle afterwards, as described by the oriented-attachment (OA) mechanism. The ratio of OAm to Fe(CO)5 used in the preparation of Fe(CO)x -OAm has a significant influence on the growth process, and subsequently the shape, size and size distribution of the FePt NPs. By adjusting the ratio and its complexing temperature, single-crystal FePt NPs with controllable size and isotropic shape were obtained. The insight into the exploration of the specific roles of the reaction conditions and the formation mechanisms provided important information for controlling the morphology of the nanoparticles. |
| 学科主题 | 纳米磁性材料研究室 |
| 原文出处 | SCI收录 |
| 公开日期 | 2013-12-16 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/9788]  |
| 专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
| 推荐引用方式 GB/T 7714 | Du J,Baoru Bian,a Weixing Xia,a Juan Du,*a Jian Zhang,a J. Ping Liu,b Zhaohui Guoc and Aru Yana. Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(II) acetylacetonate[J]. Nanoscale.,2013,102(5):2454—2459. |
| APA | Du J,&Baoru Bian,a Weixing Xia,a Juan Du,*a Jian Zhang,a J. Ping Liu,b Zhaohui Guoc and Aru Yana.(2013).Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(II) acetylacetonate.Nanoscale.,102(5),2454—2459. |
| MLA | Du J,et al."Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(II) acetylacetonate".Nanoscale. 102.5(2013):2454—2459. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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