Synthesis，characterization of a Rosin-based Epoxy Monomer and Its Comparison with a Petroleum-based Counterpart
文献类型：期刊论文
| 作者 | 刘小青，郭金山 ; Chao Li a b , Xiaoqing Liu b , Jin Zhu b , Chuanzhi Zhang b & Jinshan Guo a |
| 刊名 | Journal of Macromolecular Science Part A: Pure & Applied Chemistry
 |
| 出版日期 | 2013-02-01 |
| 期号 | 3页码:321—329 |
| 通讯作者 | 刘小青，郭金山 |
| 合作状况 | 李雨桐 |
| 中文摘要 | A bio-based epoxy derived from dehydroabietylamine was synthesized. In comparison, its petrochemical counterpart based on benzylamine was also prepared. Their chemical structures were confirmed in detail by Fourier Transform Infrared Spectra (FT-IR) and Nuclear Magnetic Resonance (1H-NMR and HSQC). The curing reactions of these synthesized epoxies with hexahydrophthalic anhydride were studied by Differential Scanning Calorimeter (DSC). The mechanical properties and thermal stability of the cured epoxies were investigated by Universal Mechanical Testing Machine, Dynamic Mechanical Analysis (DMA) and Thermogravimetric Analyzer (TGA), respectively. The results indicated that the bulky fused diterpene structure in dehydroabietylamine led to a weaker molecular motion ability and a lower cross-link density, so that the cured epoxy derived from dehydroabietylamine processed a higher glass transition temperature (167°C), but lower mechanical properties than those of the benzylamine-based one. |
| 学科主题 | 高分子材料学 |
| 原文出处 | SCI收录 |
| 公开日期 | 2013-12-16 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/9798]  |
| 专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
| 推荐引用方式 GB/T 7714 | 刘小青，郭金山,Chao Li a b , Xiaoqing Liu b , Jin Zhu b , Chuanzhi Zhang b & Jinshan Guo a. Synthesis，characterization of a Rosin-based Epoxy Monomer and Its Comparison with a Petroleum-based Counterpart[J]. Journal of Macromolecular Science Part A: Pure & Applied Chemistry,2013(3):321—329. |
| APA | 刘小青，郭金山,&Chao Li a b , Xiaoqing Liu b , Jin Zhu b , Chuanzhi Zhang b & Jinshan Guo a.(2013).Synthesis，characterization of a Rosin-based Epoxy Monomer and Its Comparison with a Petroleum-based Counterpart.Journal of Macromolecular Science Part A: Pure & Applied Chemistry(3),321—329. |
| MLA | 刘小青，郭金山,et al."Synthesis，characterization of a Rosin-based Epoxy Monomer and Its Comparison with a Petroleum-based Counterpart".Journal of Macromolecular Science Part A: Pure & Applied Chemistry .3(2013):321—329. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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