Synthesis of a bio-based polyamidoamine-epichlorohydrin resin and its application for soy-based adhesives
文献类型：期刊论文
| 作者 | 朱锦，刘小青 ; Chengsheng Gui,GuyueWang,DiWu,JinZhu n, XiaoqingLiu n |
| 刊名 | International Journal of Adhesion & Adhesives
 |
| 出版日期 | 2013-07-01 |
| 卷号 | 26期号:1页码:237—242 |
| 通讯作者 | 朱锦，刘小青 |
| 合作状况 | 李雨桐 |
| 中文摘要 | In view of sustainable development and environmental protection, renewable itaconic acid was used to synthesize a bio-based curing agent for soy-based adhesives. The bio-based curing agent, i.e., itaconic acid-based polyamidoamine-epichlorohydrin resin (IA-PAE), was characterized by RSV and 1H-NMR. Results showed that IA-PADA and IA-PAE had much lower molecular weights than commercial PAE (C-PAE). Both N-(3-chloro-2-hydroxypropyl) groups and azetidinium rings of IA-PAE could perform as functional groups in IA-PAE modified soy flour adhesive (IA-PAE-SF). The pH values affected the viscosities of IA-PAE-SF adhesives significantly but had little effect on the wet strengths. Wet strength of IA-PAE-SF on plywood (0.95 MPa) was comparable to that of C-PAE-SF and met the requirements of Chinese National Standards for type-II applications. Cross-linking networks were formed during hot-pressing process and thus, improved water resistance of IA-PAE-SF on plywood. Measurement of water-insoluble solid content of cured adhesives and observation of SEM confirmed the formation of cross-linking networks in cured IA-PAE-SF |
| 学科主题 | 高分子材料学 |
| 原文出处 | 其他国内刊物 |
| 公开日期 | 2013-12-16 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/9952]  |
| 专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
| 推荐引用方式 GB/T 7714 | 朱锦，刘小青,Chengsheng Gui,GuyueWang,DiWu,JinZhu n, XiaoqingLiu n. Synthesis of a bio-based polyamidoamine-epichlorohydrin resin and its application for soy-based adhesives[J]. International Journal of Adhesion & Adhesives,2013,26(1):237—242. |
| APA | 朱锦，刘小青,&Chengsheng Gui,GuyueWang,DiWu,JinZhu n, XiaoqingLiu n.(2013).Synthesis of a bio-based polyamidoamine-epichlorohydrin resin and its application for soy-based adhesives.International Journal of Adhesion & Adhesives,26(1),237—242. |
| MLA | 朱锦，刘小青,et al."Synthesis of a bio-based polyamidoamine-epichlorohydrin resin and its application for soy-based adhesives".International Journal of Adhesion & Adhesives 26.1(2013):237—242. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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