Synthesis and Properties of a Bio-based Epoxy Resin with High Epoxy Value and Low Viscosity
文献类型：期刊论文
| 作者 | 刘小青，朱锦 ; Songqi Ma, Xiaoqing Liu,* Libo Fan, Yanhua Jiang, Lijun Cao, Zhaobin Tang, and Jin Zhu*[a] |
| 刊名 | Chemsuschem
 |
| 出版日期 | 2013-10-17 |
| 期号 | 0页码:0—0 |
| 通讯作者 | 刘小青，朱锦 |
| 合作状况 | 李雨桐 |
| 中文摘要 | A bio-based epoxy resin (denoted TEIA) with high epoxy value (1.16) and low viscosity (0.92 Pa s, 258C) was synthesized from itaconic acid and its chemical structure was confirmed by 1H NMR and 13C NMR spectroscopy. Its curing reaction with poly(propylene glycol) bis(2-aminopropyl ether) (D230) and methyl hexahydrophthalic anhydride (MHHPA) was investigated. For comparison, the commonly used diglycidyl ether of bisphenol A (DGEBA) was also cured with the same curing agents. The results demonstrated that TEIA showed higher curing reactivity towards D230/MHHPA and lower viscosity compared with DGEBA, resulting in the better processability. Owing to its high epoxy value and unique structure, comparable or better glass transition temperature as well as mechanical properties could be obtained for the TEIA-based network relative to the DGEBA-based network. The results indicated that itaconic acid is a promising renewable feedstock for the synthesis of bio-based epoxy resin with high performance. |
| 学科主题 | 高分子材料学 |
| 原文出处 | SCI收录 |
| 公开日期 | 2013-12-16 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/10069]  |
| 专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
| 推荐引用方式 GB/T 7714 | 刘小青，朱锦,Songqi Ma, Xiaoqing Liu,* Libo Fan, Yanhua Jiang, Lijun Cao, Zhaobin Tang, and Jin Zhu*[a]. Synthesis and Properties of a Bio-based Epoxy Resin with High Epoxy Value and Low Viscosity[J]. Chemsuschem,2013(0):0—0. |
| APA | 刘小青，朱锦,&Songqi Ma, Xiaoqing Liu,* Libo Fan, Yanhua Jiang, Lijun Cao, Zhaobin Tang, and Jin Zhu*[a].(2013).Synthesis and Properties of a Bio-based Epoxy Resin with High Epoxy Value and Low Viscosity.Chemsuschem(0),0—0. |
| MLA | 刘小青，朱锦,et al."Synthesis and Properties of a Bio-based Epoxy Resin with High Epoxy Value and Low Viscosity".Chemsuschem .0(2013):0—0. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。