Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols
文献类型：期刊论文
| 作者 | Liu X(刘星)1; Li L(李莉)1; Yang W(杨伟)1; Jiang KZ(蒋可志)1; Yang KF(杨科芳)1; Zheng ZJ(郑战江)1; Xu LW(徐利文)1,2 |
| 刊名 | European Journal of Organic Chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 2013期号:26页码:5814-5819 |
| ISSN号 | 1434-193X |
| 关键词 | Asymmetric catalysis Chirality Silicon Enzymes Diols |
| 通讯作者 | 徐利文 |
| 英文摘要 | A series of silicon-containing diols are synthesized and used in lipase-catalyzed remote desymmetrization. This synthetic method is valuable in the construction of optically active silicon-stereogenic organosilicon compounds. Good enantioselectivities of the remote desymmetrization was achieved with Candida antarctica lipase B (CAL-B) (up to 90:10er). |
| 学科主题 | 物理化学与绿色催化 |
| 资助信息 | the National Natural Science Foundation of China (NSFC) (grant numbers 21173064;21205025);Zhejiang Provincial Natural Science Foundation of China (ZPNSFC) (Q12B020037);the Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT) (JTAS 2011-01-014) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000323883300006 |
| 公开日期 | 2013-12-24 |
| 源URL | [http://210.77.64.217/handle/362003/4868]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu X,Li L,Yang W,et al. Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols[J]. European Journal of Organic Chemistry,2013,2013(26):5814-5819. |
| APA | Liu X.,Li L.,Yang W.,Jiang KZ.,Yang KF.,...&Xu LW.(2013).Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols.European Journal of Organic Chemistry,2013(26),5814-5819. |
| MLA | Liu X,et al."Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols".European Journal of Organic Chemistry 2013.26(2013):5814-5819. |
入库方式： OAI收割
来源：兰州化学物理研究所
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