Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines
文献类型：期刊论文
| 作者 | Xing QF(邢其锋)1,2; Zhao, Tong1,2; Qiao, Yusen1,2; Wang L(王林)1,2; Redshaw, Carl4; Sun WH(孙文华)1,2,3 |
| 刊名 | RSC Advances
 |
| 出版日期 | 2013 |
| 卷号 | 3期号:48页码:26184-26193 |
| ISSN号 | 2046-2069 |
| 通讯作者 | Carl Redshaw ; 孙文华 |
| 英文摘要 | A series of N,N′-bis(1-(6-(1-(arylimino)ethyl)pyridin-2-yl)ethylidene)benzidines and the bi-metallic iron complexes thereof have been synthesized and fully characterized. All iron complexes, when activated by MAO or MMAO, exhibited high activities of up to 1.3×107 g mol-1 (Fe) h-1 for the polymerization of ethylene. On comparison with their mononuclear counterparts, such bi-metallic complexes not only retain a relatively high activity at elevated temperatures (up to 70 ℃), but also exhibit increased lifetimes. The polyethylenes obtained were characterized by GPC, DSC and high temperature NMR spectroscopy, which indicated multimodal and highly linear features. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China (no. 20904059) |
| 语种 | 英语 |
| WOS记录号 | WOS:000327261700096 |
| 公开日期 | 2013-12-24 |
| 源URL | [http://210.77.64.217/handle/362003/4873]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 4.Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England |
| 推荐引用方式 GB/T 7714 | Xing QF,Zhao, Tong,Qiao, Yusen,et al. Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines[J]. RSC Advances,2013,3(48):26184-26193. |
| APA | Xing QF,Zhao, Tong,Qiao, Yusen,Wang L,Redshaw, Carl,&Sun WH.(2013).Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines.RSC Advances,3(48),26184-26193. |
| MLA | Xing QF,et al."Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines".RSC Advances 3.48(2013):26184-26193. |
入库方式： OAI收割
来源：兰州化学物理研究所
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