Modification of TiO2 with sulfate and phosphate for enhanced eosin Y-sensitized hydrogen evolution under visible light illumination
文献类型：期刊论文
| 作者 | Liu X(刘兴)1; Li YX(李越湘)1; Peng SQ(彭绍琴)1; Lu GX(吕功煊)2 ; Li SB(李树本)2
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| 刊名 | Photochemical & Photobiological Sciences
 |
| 出版日期 | 2013 |
| 卷号 | 12期号:10页码:1903-1910 |
| ISSN号 | 1474-905X |
| 通讯作者 | 李越湘 |
| 英文摘要 | TiO2 was modified with sulfate and phosphate (denoted as S/TiO2 and P/TiO2) through a simple sulfuric or phosphoric acid treatment. A strong coordination bond forms between sulfate or phosphate and Ti4+ of TiO2. Eosin Y (EY)-sensitized S/TiO2 and P/TiO2 (Pt as a co-catalyst and triethanolamine as a sacrificial electron donor) exhibit enhanced photocatalytic activity for hydrogen evolution under visible light illumination (λ> 420 nm) compared to that of EY-sensitized TiO2. The conduction band (CB) edges of S/TiO2 and P/TiO2 shift toward the negative, and the hydrogen bond interaction between the reduced radical EY•–H and S/TiO2 or P/TiO2 is enhanced due to the inducing effect of the bound sulfate and phosphate. Thus, the photocatalytic hydrogen evolution is promoted. The effects of the concentration of the sulfuric or phosphoric acid as well as concentration of EY on the sensitization hydrogen evolution were investigated. The possible mechanism was discussed. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Nature Science Foundation of China (21163012);the National Basic Research Program of China (2009CB220003);the Innovation Fund for Graduate Student of Nanchang University (cx2011007) |
| 语种 | 英语 |
| WOS记录号 | WOS:000324890300018 |
| 公开日期 | 2013-12-30 |
| 源URL | [http://210.77.64.217/handle/362003/4932]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 作者单位 | 1.Nanchang Univ, Dept Chem, Nanchang 330031, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu X,Li YX,Peng SQ,et al. Modification of TiO2 with sulfate and phosphate for enhanced eosin Y-sensitized hydrogen evolution under visible light illumination[J]. Photochemical & Photobiological Sciences,2013,12(10):1903-1910. |
| APA | Liu X,Li YX,Peng SQ,Lu GX,&Li SB.(2013).Modification of TiO2 with sulfate and phosphate for enhanced eosin Y-sensitized hydrogen evolution under visible light illumination.Photochemical & Photobiological Sciences,12(10),1903-1910. |
| MLA | Liu X,et al."Modification of TiO2 with sulfate and phosphate for enhanced eosin Y-sensitized hydrogen evolution under visible light illumination".Photochemical & Photobiological Sciences 12.10(2013):1903-1910. |
入库方式： OAI收割
来源：兰州化学物理研究所
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