Preparation and crystal structure of [enH(2)](0.5)[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine)
文献类型：期刊论文
| 作者 | Kumada, Nobuhiro1; Kumon, Junichi1; Miyagawa, Kazuya1; Yonesaki, Yoshinori1; Takei, Takahiro1; Kinomura, Nobukazu1; Wang, Dan2; Yu, Ranbo3 |
| 刊名 | JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
 |
| 出版日期 | 2010-03-01 |
| 卷号 | 118期号:1375页码:236-240 |
| 关键词 | Crystal structure Phosphate Rare-earth metal elements |
| ISSN号 | 1882-0743 |
| 通讯作者 | Kumada, N |
| 英文摘要 | Single crystals of an organically templated holmium hydrogen phosphate sulfate, [enH(2)](0.5)[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine) were prepared by hydrothermal reaction and its crystal structure was determined by single crystal X-ray diffraction data. This compound crystallized in the monoclinic system, space group P2(1)/a (No. 14) and the unit cell parameters are a 12.938(5), b = 6.834(3), c = 9.100(2) angstrom, and beta=88.12(2)degrees. The crystal structure is similar to that of [enH(2)](0.5)[Ce(HPO4)(SO4)(H2O)] which had a layered structure built tip by Cc centered polyhedra and HPO4 and SO4 tetrahedra, and the diprotonated ethylenediamine cations were located in the interlayer. For other rare earth elements two types of compounds were obtained tinder hydrothermal conditions. The compounds of R = La, Pr, Nd, Sm and Eu are isostructural with [enH(2)](0.5)[Ce(HPO4)(SO4)(H2O)] and those of Gd, Th, Dy, Er and Yb with [enH(2)](0.5)[Ho(HPO4)(SO4)(H2O)]. The unit cell volumes of these compounds decrease by lanthanide contraction. The compounds of R except La, Sm and Eu exhibited the Curie-Weiss paramagnetic behavior. (C)2010 The Ceramic Society of Japan. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Materials Science, Ceramics |
| 研究领域[WOS] | Materials Science |
| 关键词[WOS] | ZIRCONIUM-PHOSPHATE ; FLUORIDE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000275804100016 |
| 公开日期 | 2013-11-27 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6204]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Univ Yamanashi, Interdisciplinary Grad Sch Med & Engn, Dept Res, Yamanashi 4008511, Japan 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Multiphase & Complex Syst, Beijing 100080, Peoples R China 3.Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kumada, Nobuhiro,Kumon, Junichi,Miyagawa, Kazuya,et al. Preparation and crystal structure of [enH(2)](0.5)[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine)[J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN,2010,118(1375):236-240. |
| APA | Kumada, Nobuhiro.,Kumon, Junichi.,Miyagawa, Kazuya.,Yonesaki, Yoshinori.,Takei, Takahiro.,...&Yu, Ranbo.(2010).Preparation and crystal structure of [enH(2)](0.5)[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine).JOURNAL OF THE CERAMIC SOCIETY OF JAPAN,118(1375),236-240. |
| MLA | Kumada, Nobuhiro,et al."Preparation and crystal structure of [enH(2)](0.5)[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine)".JOURNAL OF THE CERAMIC SOCIETY OF JAPAN 118.1375(2010):236-240. |
入库方式： OAI收割
来源：过程工程研究所
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