Degradation of poly(ethylene terephthalate) using ionic liquids
文献类型：期刊论文
| 作者 | Wang, Hui1; Li, Zengxi1; Liu, Yanqing1; Zhang, Xiangping2; Zhang, Suojiang2 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2009 |
| 卷号 | 11期号:10页码:1568-1575 |
| 关键词 | SOFT-DRINK BOTTLES SULFURIC-ACID CHLORIDE DEPOLYMERIZATION HYDROLYSIS GLYCOLYSIS WASTE POLYETHYLENE DISSOLUTION CELLULOSE |
| ISSN号 | 1463-9262 |
| 通讯作者 | Wang, H |
| 英文摘要 | The degradation of poly(ethylene terephthalate) (PET) was successfully achieved using ionic liquids. The products were separated according to their solubilities in boiling water. Average molecular weights of the main product were determined by gel permeation chromatography (GPC). The physicochemical properties of the product have been characterized by scanning electron microscopy equipped with an energy dispersive X-ray analyzer (SEM/EDX), X-ray diffractometer, infrared spectrometric analyzer, differential scanning calorimeter, and thermogravimetric analysis instrument. The influences of experimental parameters, such as the reaction time, reaction temperature, and addition of different catalysts on the solubility of PET were investigated. A study on the recycling of the ionic liquid shows that ionic liquid could be used repeatedly. Moreover, the solubility of PET in the recycled ionic liquid is higher than that in fresh ionic liquid. Further study shows that the increase of solubility in the recycled ionic liquid is attributable to the presence of a minor amount of water. A mechanism of the degradation of PET in 1-butyl-3-methylimidazolium chloride ([bmim]Cl) was proposed. In addition, the kinetics of this reaction was investigated. Results show that this degradation process is a first-order kinetic reaction and the activation energy is 232.79 kJ mol(-1). |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SOFT-DRINK BOTTLES ; SULFURIC-ACID ; CHLORIDE ; DEPOLYMERIZATION ; HYDROLYSIS ; GLYCOLYSIS ; WASTE ; POLYETHYLENE ; DISSOLUTION ; CELLULOSE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000270542400015 |
| 公开日期 | 2013-12-11 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6778]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Hui,Li, Zengxi,Liu, Yanqing,et al. Degradation of poly(ethylene terephthalate) using ionic liquids[J]. GREEN CHEMISTRY,2009,11(10):1568-1575. |
| APA | Wang, Hui,Li, Zengxi,Liu, Yanqing,Zhang, Xiangping,&Zhang, Suojiang.(2009).Degradation of poly(ethylene terephthalate) using ionic liquids.GREEN CHEMISTRY,11(10),1568-1575. |
| MLA | Wang, Hui,et al."Degradation of poly(ethylene terephthalate) using ionic liquids".GREEN CHEMISTRY 11.10(2009):1568-1575. |
入库方式： OAI收割
来源：过程工程研究所
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