Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production
文献类型：期刊论文
| 作者 | Biboum, Rosa N.1; Keita, Bineta1; Franger, Sylvain2; Njiki, Charles P. Nanseu1; Zhang, Guangjin3; Zhang, Jie4; Liu, Tianbo4; Mbomekalle, Israel-Martyr5; Nadjo, Louis1 |
| 刊名 | MATERIALS
 |
| 出版日期 | 2010 |
| 卷号 | 3期号:1页码:741-754 |
| 关键词 | green chemistry palladium nanoparticles nanostructures vanadium-substituted polyoxotungstate self-assembly hydrogen evolution reaction |
| ISSN号 | 1996-1944 |
| 通讯作者 | Keita, B |
| 英文摘要 | Green-chemistry type procedures were used to synthesize Pd-0 nanostructures encapsulated by a vanadium-substituted Wells-Dawson-type polyoxometalate (Pd-0@POM). The cyclic voltammogram run with the Pd-0@POM-modified glassy carbon electrode shows well-defined waves, associated with Pd-0 nanostructures and the V-V/V-IV redox couple. The Pd-0@POM-modified electrode displayed remarkably reproducible cyclic voltammetry patterns. The hydrogen evolution reaction (HER) was selected as an illustrative example to test the electrocatalytic behavior of the electrode. The kinetic parameters of the HER show the high efficiency of the Pd-0@POM-modified electrode. This is the first example of electrochemical characterization of a modified electrode based on a vanado-tungstic POM and Pd-0 nanostructures. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Materials Science, Multidisciplinary |
| 研究领域[WOS] | Materials Science |
| 关键词[WOS] | ONE-STEP SYNTHESIS ; OXIDE FUEL-CELLS ; METAL NANOPARTICLES ; AQUEOUS-SOLUTION ; COLLOIDAL SOLUTIONS ; FACILE SYNTHESIS ; PALLADIUM ; EVOLUTION ; TRANSITION ; REDUCTION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000298240100040 |
| 公开日期 | 2013-11-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6249]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Univ Paris 11, CNRS, Chim Phys Lab, Grp Electrochim & Photoelectrochime,UMR 800, F-91405 Orsay, France 2.Univ Paris 11, CNRS, Lab Physicochim Etat Solide, ICMMO,UMR8182, F-91405 Orsay, France 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc Engn, Beijing 100190, Peoples R China 4.Lehigh Univ, Dept Chem, Bethlehem, PA 18015 USA 5.Univ Versailles St Quentin, Inst Lavoisier, UMR 8180, F-78035 Versailles, France |
| 推荐引用方式 GB/T 7714 | Biboum, Rosa N.,Keita, Bineta,Franger, Sylvain,et al. Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production[J]. MATERIALS,2010,3(1):741-754. |
| APA | Biboum, Rosa N..,Keita, Bineta.,Franger, Sylvain.,Njiki, Charles P. Nanseu.,Zhang, Guangjin.,...&Nadjo, Louis.(2010).Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production.MATERIALS,3(1),741-754. |
| MLA | Biboum, Rosa N.,et al."Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production".MATERIALS 3.1(2010):741-754. |
入库方式： OAI收割
来源：过程工程研究所
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