Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers
文献类型：期刊论文
| 作者 | Wang, Yibo1,2; Gao, Lihua2; Han, Lijun1; Zhang, Suojiang1; Feng, Lujia2 |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2009-12-16 |
| 卷号 | 938期号:1-3页码:214-220 |
| 关键词 | Hydrothermal synthesis Coordination polymers Lanthanides Carboxylate ligands X-ray diffraction |
| ISSN号 | 0022-2860 |
| 通讯作者 | Zhang, SJ |
| 英文摘要 | Two novel isostructure open frameworks of Ln(III), [Ln(L)(H(2)O) 1 5H(2)O](n), [Ln = Pr(1), Eu(2)], have been successfully synthesized using multi functional organic compound 7,8,4'-tricarboxymethoxyisoflavone (L) as a linker through hydrothermal technique. Compounds 1 and 2 consist of 2D networks, which are further assembled into 3D architecture with 1D channels constructed by coordination bonds and the lattice water molecules array in lines occupying these voids via hydrogen bonds. in these compounds, L only exhibit one coordination mode coordinating to Ln(III). and four oxygen atoms from two carboxylate groups and two carboxymethoxy groups of one L coordinate to one Ln(III), simultaneously. The thermogravimetric analyses of these compounds show that the coordinated water and lattice water are lost in two steps, and the final residues are lanthanide oxides (C) 2009 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | METAL-ORGANIC FRAMEWORK ; CRYSTAL-STRUCTURE ; BUILDING UNITS ; DESIGN ; CHEMISTRY ; ACID ; ISOFLAVONES ; COMPLEXES ; MOLECULES ; CHANNELS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272896300032 |
| 公开日期 | 2013-11-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6529]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Res Lab Green Chem & Technol, Beijing 100080, Peoples R China 2.Beijing Technol & Business Univ, Sch Chem & Environm Engn, Beijing 100037, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yibo,Gao, Lihua,Han, Lijun,et al. Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers[J]. JOURNAL OF MOLECULAR STRUCTURE,2009,938(1-3):214-220. |
| APA | Wang, Yibo,Gao, Lihua,Han, Lijun,Zhang, Suojiang,&Feng, Lujia.(2009).Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers.JOURNAL OF MOLECULAR STRUCTURE,938(1-3),214-220. |
| MLA | Wang, Yibo,et al."Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers".JOURNAL OF MOLECULAR STRUCTURE 938.1-3(2009):214-220. |
入库方式： OAI收割
来源：过程工程研究所
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