Apparent Kinetics for Electrosynthesis Process of Chromic Acid
文献类型：期刊论文
| 作者 | Li Cheng-wei1,2; Wang Fu-an1; Qi Tao3; Wang Rui-lin2; Tang Xiao-hong2; Zhang Yong-qiang2 |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2009-07-25 |
| 卷号 | 25期号:4页码:532-536 |
| 关键词 | Apparent kinetics Chromic acid Electrosynthesis method Kinetic model |
| ISSN号 | 1005-9040 |
| 通讯作者 | Wang, FA |
| 英文摘要 | A new green technique for producing chromic acid via an electrosynthesis method was studied. The kinetic experiments were carried out on the direct electrosynthesis reaction of chromic acid from sodium dichromate in a self-made electrosynthesis reactor with a multiple-unit metal oxides combination anode, a stainless steel cathode, and a reinforcing combination Nafion (R) 324 cation exchange membrane. The apparent kinetic data were experimentally measured at different reaction time under different reaction conditions by relating many essential cell processes and their interaction, as well as their synergistic effect to the whole electrochemical synthesis process. The results show that the electrosynthesis reaction process follows a quasi-first-order reaction kinetic characteristic. The apparent kinetic model of the electrosynthesis reaction was established, and kinetic parameters were calculated. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ELECTROCHEMICAL SYNTHESIS PROCESS ; PLUS WATER ; SODIUM DICHROMATE ; 333.15 K ; SOLUBILITIES ; REMOVAL ; ETHANOL ; NIACIN |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000269232100028 |
| 公开日期 | 2013-12-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6633]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Zhengzhou Univ, Coll Chem Engn, Zhengzhou 450002, Peoples R China 2.Henan Inst Educ, Dept Chem, Zhengzhou 450014, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Cheng-wei,Wang Fu-an,Qi Tao,et al. Apparent Kinetics for Electrosynthesis Process of Chromic Acid[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2009,25(4):532-536. |
| APA | Li Cheng-wei,Wang Fu-an,Qi Tao,Wang Rui-lin,Tang Xiao-hong,&Zhang Yong-qiang.(2009).Apparent Kinetics for Electrosynthesis Process of Chromic Acid.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,25(4),532-536. |
| MLA | Li Cheng-wei,et al."Apparent Kinetics for Electrosynthesis Process of Chromic Acid".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 25.4(2009):532-536. |
入库方式： OAI收割
来源：过程工程研究所
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