A general diffusion model for mass transfer in colloidal liquid aphron systems
文献类型:期刊论文
作者 | He, Yi1,2; Wu, Zhichun1; Mao, Zai-Sha1 |
刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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出版日期 | 2009-04-15 |
卷号 | 338期号:1-3页码:25-32 |
关键词 | Colloidal liquid aphrons (CLAs) Mass transfer Interface Surfactant Diffusion Micelle |
ISSN号 | 0927-7757 |
通讯作者 | Mao, ZS |
英文摘要 | A general diffusion model for Solute transport in colloidal liquid aphron (CLA) systems is proposed in terms of diffusive mass transfer. The model incorporates five specific mass transfer resistances occurred at interfaces and in liquid phases. The experimental cases conducted in CIA systems are simulated successfully to verify the validity of numerical procedure and underlying assumptions. Both numerical results and experimental data show that apparent diffusion coefficient of CLA systems is far smaller than that in pure solvent systems. This can be well explained considering the role of surfactants, which cause the interfacial resistance and micelles (or reverse micelles) hindrance. The interfacial resistances of adsorbed surfactants and formed micelles (or reverse micelles) hindrance are estimated by the simplex method from the experimental data. It is shown that both interfacial transfer coefficient and micellar diffusion coefficient decrease with the increase of surfactants concentration. (C) 2008 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | PREDISPERSED SOLVENT-EXTRACTION ; STABILITY ; COEFFICIENTS ; SURFACTANTS ; CLAS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000264707100005 |
公开日期 | 2013-12-09 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/6683] ![]() |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | He, Yi,Wu, Zhichun,Mao, Zai-Sha. A general diffusion model for mass transfer in colloidal liquid aphron systems[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2009,338(1-3):25-32. |
APA | He, Yi,Wu, Zhichun,&Mao, Zai-Sha.(2009).A general diffusion model for mass transfer in colloidal liquid aphron systems.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,338(1-3),25-32. |
MLA | He, Yi,et al."A general diffusion model for mass transfer in colloidal liquid aphron systems".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 338.1-3(2009):25-32. |
入库方式: OAI收割
来源:过程工程研究所
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