Action of Molecular Kinetic Energy on a Gas-solid Chromatography
文献类型：期刊论文
| 作者 | Zhang Da-Li1; Ke Jia-Jun2; Lu Li-Zhu2 |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2009-04-10 |
| 卷号 | 30期号:4页码:777-780 |
| 关键词 | Molecular ehermoclynamic movement Migratory activation energy Maxwell distribution of energy Principle of equiparation of energy Gas-solid chromatography Slip mechanism |
| ISSN号 | 0251-0790 |
| 通讯作者 | Zhang, DL |
| 英文摘要 | The migration velocity, the migratory activation energy and the action of molecular motion on migration were researched for five alkanes in the gas-solid chromatography of N(2)/GDX-101 system. Maxwell distribution of energy which originally shows the molecule fraction of molecular translation energy exceeding E, was used for expressing the time fraction of the translation energy exceeding E. The kinetic energy of rotation and vibration was expressed by the times of kT/2 in the light of the principle of equiparation of energy, to modify the ideal equation. The migratory activation energy (E) which is calculated with the rate equation, could well explain the migration velocity. The kinetic energy of rotation and vibration observably influences E. These properties were also authenticated with the estimate of statistical thermodynamics. The calculation showed that E was obviously smaller than the desorption enthalpy (Delta H(Desorption)). The solute migration might not reach the state of desorption. The solute driven by mobile phase should mainly slip under the state of adsorption. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | MASS SPECTROMETRY ; DIFFUSION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000265665700028 |
| 公开日期 | 2013-12-09 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6687]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Beijing Union Univ, Biochem Engn Coll, Beijing 100023, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Da-Li,Ke Jia-Jun,Lu Li-Zhu. Action of Molecular Kinetic Energy on a Gas-solid Chromatography[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2009,30(4):777-780. |
| APA | Zhang Da-Li,Ke Jia-Jun,&Lu Li-Zhu.(2009).Action of Molecular Kinetic Energy on a Gas-solid Chromatography.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,30(4),777-780. |
| MLA | Zhang Da-Li,et al."Action of Molecular Kinetic Energy on a Gas-solid Chromatography".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 30.4(2009):777-780. |
入库方式： OAI收割
来源：过程工程研究所
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