Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids
文献类型：期刊论文
| 作者 | Gao, Lixia1,2; Wang, Lina1; Qi, Tao1; Chu, Jinglong1; Qu, Jingkui1 |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 2009 |
| 卷号 | 156期号:3页码:P49-P55 |
| 关键词 | TEMPERATURE MOLTEN-SALT IN-SITU STM COBALT-ALUMINUM ALLOYS CHLORIDE MOLTEN ELECTRICAL CONDUCTIVITIES PHYSICAL-PROPERTIES PHASE-TRANSITIONS RAMAN-SPECTRA HOLE THEORY C-13 NMR |
| ISSN号 | 0013-4651 |
| 通讯作者 | Gao, LX |
| 英文摘要 | A series of TiCl(4)-based ionic liquids (ILs) was synthesized by mixing TiCl(4) with quaternary ammonium, pyridinium, and imidazolium chlorogenated salt, respectively. The structure and composition of the ILs were studied with Fourier transform ion cyclotron resonance mass spectrometry. IR, and Raman spectra. The primary anions of the TiCl(4)-based ILs were TiCl(9)(-) and TiCl(6)(2-), whose amounts were different by variation of the molar ratio of TiCl(4) to organic halogenated salt. The physical properties such as the phase transition behavior, surface tension, density, viscosity, and conductivity of these ILs were also investigated. Temperature-dependent viscocity and conductivity of the ILs followed the Vogel-Tammann-Fulcher equation, and the best-fit parameters had been estimated, together with the lienar fitting parameters for the density. The conductivity and viscosity of the TiCl(4)-based ILs were controlled by the ion mobility and the availability of voids with suitable dimensions. Hole theory could well explain the physicochemical properties of the TiCl(4)-based ILs. (c) 2008 The Electrochemical Society. [DOI: 10.1149/1.3046160] All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Electrochemistry ; Materials Science, Coatings & Films |
| 研究领域[WOS] | Electrochemistry ; Materials Science |
| 关键词[WOS] | TEMPERATURE MOLTEN-SALT ; IN-SITU STM ; COBALT-ALUMINUM ALLOYS ; CHLORIDE MOLTEN ; ELECTRICAL CONDUCTIVITIES ; PHYSICAL-PROPERTIES ; PHASE-TRANSITIONS ; RAMAN-SPECTRA ; HOLE THEORY ; C-13 NMR |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000265837900073 |
| 公开日期 | 2013-12-11 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6791]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Lixia,Wang, Lina,Qi, Tao,et al. Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2009,156(3):P49-P55. |
| APA | Gao, Lixia,Wang, Lina,Qi, Tao,Chu, Jinglong,&Qu, Jingkui.(2009).Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,156(3),P49-P55. |
| MLA | Gao, Lixia,et al."Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 156.3(2009):P49-P55. |
入库方式： OAI收割
来源：过程工程研究所
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