Preparation and Characterization of Hydrogels with Lyotropic Liquid Crystallite as Template
文献类型：期刊论文
| 作者 | Lu Cuixiang1,2; Du Zhuwei1 ; Li Haoran1
|
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2009-02-14 |
| 卷号 | 67期号:3页码:238-244 |
| 关键词 | polyacrylamide lyotropic liquid crystal (LLC) hydrogel swelling ratio |
| ISSN号 | 0567-7351 |
| 通讯作者 | Lu, CX |
| 英文摘要 | Polyacrylamide (PAAm) hydrogels were synthesized by acrylamide polymerization in lyotropic liquid crystal (LLC) phase formed by surfactant Brij 58 solution. The morphology, structure and swelling property of the hydrogels were characterized. SEM images showed that photopolymerization of acrylamide monomers in organized assemblies with concentration between 10% and 40% formed highly ordered hydrogels. The pore size of the LLC hydrogels was 1 similar to 2 mu m, which was about one fortieth of that of the traditional hydrogel. Phase reversal and phase separation occurred when concentration of Brij 58 was higher than 50%. Porosity of the hydrogels decreased with the increase of Brij 58 concentration. Characteristic peaks of FTIR spectra corresponding to carbonyl and amino groups shifted to lower wavenumber, indicating that more inter-molecular hydrogen bonds in LLC PAAm hydrogels. The LLC hydrogel kept the characteristic feature of sensitivity to pH as traditional hydrogel and a higher swelling ratio could be achieved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | PHOTOPOLYMERIZATION ; POLYMERS ; BEHAVIOR |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000264250600010 |
| 公开日期 | 2013-12-10 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6725]  |
| 专题 | 过程工程研究所_生化工程国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu Cuixiang,Du Zhuwei,Li Haoran. Preparation and Characterization of Hydrogels with Lyotropic Liquid Crystallite as Template[J]. ACTA CHIMICA SINICA,2009,67(3):238-244. |
| APA | Lu Cuixiang,Du Zhuwei,&Li Haoran.(2009).Preparation and Characterization of Hydrogels with Lyotropic Liquid Crystallite as Template.ACTA CHIMICA SINICA,67(3),238-244. |
| MLA | Lu Cuixiang,et al."Preparation and Characterization of Hydrogels with Lyotropic Liquid Crystallite as Template".ACTA CHIMICA SINICA 67.3(2009):238-244. |
入库方式： OAI收割
来源：过程工程研究所
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