Characterization of Solid Acid Catalysts and Their Reactivity in the Glycolysis of Poly(ethylene terephthalate)
文献类型：期刊论文
| 作者 | Zhu, Minli1; Li, Zengxi1; Wang, Qian1,2; Zhou, Xueyuan1,2; Lu, Xingmei2 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2012-09-12 |
| 卷号 | 51期号:36页码:11659-11666 |
| 关键词 | polyethylene terephthalate supercritical methanol nanocrystalline co3o4 superacid catalyst ethylene-glycol depolymerization wastes tio2-zro2 kinetics liquid |
| ISSN号 | 0888-5885 |
| 其他题名 | Ind. Eng. Chem. Res. |
| 中文摘要 | Glycolysis of poly(ethylene terephthalate) with ethylene glycol was carried out with the catalysts of sulfated cobalt oxide (SO42-/Co3O4) and zinc-modified sulfated cobalt oxide (SO42-/Co-Zn-O). The catalysts prepared at different calcination temperatures have been characterized by various techniques. These techniques include X-ray diffraction, Raman spectrum, gas adsorption analysis, NH3-temperature programmed desorption, and IR spectroscopy of pyridine adsorption. The performances of these catalysts on the depolymerization of PET under mild conditions were studied, and relationships between the catalysts' textural properties, the surface acidity, and the catalytic activity have been investigated. The experimental results showed that the catalytic activity on glycolysis of PET was significantly improved by the catalysts of binary sulfur oxides of SO42-/Co-Zn-O. The conversion of PET obtained on SO42-/Co-Zn-O-300 degrees C was 96%, and the selectivity of BHET was 75%, after 3 h at 180 degrees C under atmospheric pressure. |
| 英文摘要 | Glycolysis of poly(ethylene terephthalate) with ethylene glycol was carried out with the catalysts of sulfated cobalt oxide (SO42-/Co3O4) and zinc-modified sulfated cobalt oxide (SO42-/Co-Zn-O). The catalysts prepared at different calcination temperatures have been characterized by various techniques. These techniques include X-ray diffraction, Raman spectrum, gas adsorption analysis, NH3-temperature programmed desorption, and IR spectroscopy of pyridine adsorption. The performances of these catalysts on the depolymerization of PET under mild conditions were studied, and relationships between the catalysts' textural properties, the surface acidity, and the catalytic activity have been investigated. The experimental results showed that the catalytic activity on glycolysis of PET was significantly improved by the catalysts of binary sulfur oxides of SO42-/Co-Zn-O. The conversion of PET obtained on SO42-/Co-Zn-O-300 degrees C was 96%, and the selectivity of BHET was 75%, after 3 h at 180 degrees C under atmospheric pressure. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | POLYETHYLENE TEREPHTHALATE ; SUPERCRITICAL METHANOL ; NANOCRYSTALLINE CO3O4 ; SUPERACID CATALYST ; ETHYLENE-GLYCOL ; DEPOLYMERIZATION ; WASTES ; TIO2-ZRO2 ; KINETICS ; LIQUID |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000308575300010 |
| 公开日期 | 2013-11-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6276]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Minli,Li, Zengxi,Wang, Qian,et al. Characterization of Solid Acid Catalysts and Their Reactivity in the Glycolysis of Poly(ethylene terephthalate)[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2012,51(36):11659-11666. |
| APA | Zhu, Minli,Li, Zengxi,Wang, Qian,Zhou, Xueyuan,&Lu, Xingmei.(2012).Characterization of Solid Acid Catalysts and Their Reactivity in the Glycolysis of Poly(ethylene terephthalate).INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,51(36),11659-11666. |
| MLA | Zhu, Minli,et al."Characterization of Solid Acid Catalysts and Their Reactivity in the Glycolysis of Poly(ethylene terephthalate)".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 51.36(2012):11659-11666. |
入库方式： OAI收割
来源：过程工程研究所
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