Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing
文献类型：期刊论文
| 作者 | Gurau, Gabriela1,2; Wang, Hui1,2; Qiao, Yun3; Lu, Xingmei3; Zhang, Suojiang3; Rogers, Robin D.1,2,3 |
| 刊名 | PURE AND APPLIED CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 84期号:3页码:745-754 |
| 关键词 | cellulose chitin dissolution halide-free synthesis ionic liquids one-pot synthesis |
| ISSN号 | 0033-4545 |
| 其他题名 | Pure Appl. Chem. |
| 中文摘要 | Ionic liquids (ILs) are desirable for use in a large number of applications because of their unique properties; however, compositions comprising only a single IL are expensive to synthesize and difficult to purify, and the widely used chloride-based ILs can be toxic and corrosive. Therefore, there is a need for new IL compositions that minimize common dis advantages encountered with single IL composition and synthetic methods which avoid halide intermediates. In this study, IL mixtures, which are chloride-free, were synthesized by a one-pot process, and the mixtures were used to dissolve biopolymers. The synthesized IL mixtures show high capability to dissolve the two exemplary biopolymers, cellulose and chitin. |
| 英文摘要 | Ionic liquids (ILs) are desirable for use in a large number of applications because of their unique properties; however, compositions comprising only a single IL are expensive to synthesize and difficult to purify, and the widely used chloride-based ILs can be toxic and corrosive. Therefore, there is a need for new IL compositions that minimize common dis advantages encountered with single IL composition and synthetic methods which avoid halide intermediates. In this study, IL mixtures, which are chloride-free, were synthesized by a one-pot process, and the mixtures were used to dissolve biopolymers. The synthesized IL mixtures show high capability to dissolve the two exemplary biopolymers, cellulose and chitin. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | DISSOLUTION ; SOLVENTS ; CELLULOSE ; FIBERS ; CHITIN ; WOOD ; IMIDAZOLIUM ; EXTRACTION ; LIGNIN |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000301282100024 |
| 公开日期 | 2013-11-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6279]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA 2.Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gurau, Gabriela,Wang, Hui,Qiao, Yun,et al. Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing[J]. PURE AND APPLIED CHEMISTRY,2012,84(3):745-754. |
| APA | Gurau, Gabriela,Wang, Hui,Qiao, Yun,Lu, Xingmei,Zhang, Suojiang,&Rogers, Robin D..(2012).Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing.PURE AND APPLIED CHEMISTRY,84(3),745-754. |
| MLA | Gurau, Gabriela,et al."Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing".PURE AND APPLIED CHEMISTRY 84.3(2012):745-754. |
入库方式： OAI收割
来源：过程工程研究所
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