中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Corrosion of Several Typical Alloys in Concentrated Sodium Hydroxide Solution with Chloride Between 180 degrees C and 240 degrees C

文献类型:期刊论文

作者Ju, S.1,2; Zhang, Y.1,2; Shang, D.1,2; Chen, F.1,2; Wang, Y.; Zhang, Y.1,2
刊名CORROSION
出版日期2011-03-01
卷号67期号:3页码:036001
关键词alkalies and salts autoclave testing chloride corrosion rate nickel stainless steel
ISSN号0010-9312
其他题名Corrosion
中文摘要The corrosion rates of two nickel-based alloys, Alloy 400 (UNS N04400) and Alloy C-276 (UNS N10276), and two stainless steels, Type 316L (UNS 31603) and Type 304 (UNS S30400), in a concentrated sodium hydroxide (NaOH) solution (45 mass%) containing sodium chloride (NaCl, 15 g/L) between 180 degrees C to 240 degrees C were studied. Methods, such as weight variation, color changes, scanning electron microscopy (SEM), and energy spectrum analysis of the samples during tests were conducted to evaluate the corrosion of those alloy samples. Results showed that the corrosion rate of Alloy C-276 in high-alkali solution with chloride at high temperature is the lowest, about 0.022 mm/y to 0.073 mm/y, then Alloy 400, about 0.09 mm/y to 0.60 mm/y, and finally Types 304 and 316L, about 1.0 mm/y to 16.4 mm/y. Thus, the corrosion rate of Alloy C-276 is 14 to 180 times lower than that of mild steel used in the "Bayer" process. The energy spectrum analysis showed that after testing, Alloy C-276 had a very thin oxide layer. Alloy 400 can exhibit pitting corrosion when some S(2-) anions exist in the solution and forms an oxide film when concentrated Cl(-) exists in the solution. For Types 304 and 316L, cracks formed on their surface, showing that they have a high tendency to stress corrosion.
英文摘要The corrosion rates of two nickel-based alloys, Alloy 400 (UNS N04400) and Alloy C-276 (UNS N10276), and two stainless steels, Type 316L (UNS 31603) and Type 304 (UNS S30400), in a concentrated sodium hydroxide (NaOH) solution (45 mass%) containing sodium chloride (NaCl, 15 g/L) between 180 degrees C to 240 degrees C were studied. Methods, such as weight variation, color changes, scanning electron microscopy (SEM), and energy spectrum analysis of the samples during tests were conducted to evaluate the corrosion of those alloy samples. Results showed that the corrosion rate of Alloy C-276 in high-alkali solution with chloride at high temperature is the lowest, about 0.022 mm/y to 0.073 mm/y, then Alloy 400, about 0.09 mm/y to 0.60 mm/y, and finally Types 304 and 316L, about 1.0 mm/y to 16.4 mm/y. Thus, the corrosion rate of Alloy C-276 is 14 to 180 times lower than that of mild steel used in the "Bayer" process. The energy spectrum analysis showed that after testing, Alloy C-276 had a very thin oxide layer. Alloy 400 can exhibit pitting corrosion when some S(2-) anions exist in the solution and forms an oxide film when concentrated Cl(-) exists in the solution. For Types 304 and 316L, cracks formed on their surface, showing that they have a high tendency to stress corrosion.
WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
研究领域[WOS]Materials Science ; Metallurgy & Metallurgical Engineering
关键词[WOS]NAOH
收录类别SCI
原文出处://WOS:000294545300007
语种英语
WOS记录号WOS:000294545300007
公开日期2013-11-28
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/6290]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Natl Engn Lab, Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Ju, S.,Zhang, Y.,Shang, D.,et al. Corrosion of Several Typical Alloys in Concentrated Sodium Hydroxide Solution with Chloride Between 180 degrees C and 240 degrees C[J]. CORROSION,2011,67(3):036001.
APA Ju, S.,Zhang, Y.,Shang, D.,Chen, F.,Wang, Y.,&Zhang, Y..(2011).Corrosion of Several Typical Alloys in Concentrated Sodium Hydroxide Solution with Chloride Between 180 degrees C and 240 degrees C.CORROSION,67(3),036001.
MLA Ju, S.,et al."Corrosion of Several Typical Alloys in Concentrated Sodium Hydroxide Solution with Chloride Between 180 degrees C and 240 degrees C".CORROSION 67.3(2011):036001.

入库方式: OAI收割

来源:过程工程研究所

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