中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Phase Diagrams for the Ternary Na2O-Al2O3-H2O System at (150 and 180) degrees C

文献类型:期刊论文

作者Jin, Wei1,2; Zheng, Shili1; Du, Hao1; Xu, Hongbin1; Wang, Shaona1; Zhang, Yi1
刊名JOURNAL OF CHEMICAL AND ENGINEERING DATA
出版日期2010-07-01
卷号55期号:7页码:2470-2473
关键词alkaline-solutions sodium aluminate
ISSN号0021-9568
其他题名J. Chem. Eng. Data
中文摘要The full alkali concentration range phase diagrams of the Na2O-Al2O3-H2O system were constructed at (150 and 180) degrees C. The compositions of the clear liquids and wet solid phases were analyzed by inductively coupled plasma atomic emission spectrometry (ICP-AES), and the results show that, as the Na2O concentration increases, the Al2O3 solubility initially increases monotonically, to maximum values of 100 w (mass fraction) = 33.58 and 35.86 at (150 and 180) degrees C, respectively, and then decreases. At both temperatures, the solid phases were determined to be Al2O3 center dot H2O, Na2O center dot Al2O3 center dot 2.5H(2)O, Na2O center dot Al2O3, and NaOH by X-ray diffraction coupled with Schreinemaker's method. The phase diagrams indicate that, as the temperature increases, the Na2O center dot Al2O3 center dot 2.5H(2)O phase region shrinks, while that of the Na2O center dot Al2O3 phase expands.
英文摘要The full alkali concentration range phase diagrams of the Na2O-Al2O3-H2O system were constructed at (150 and 180) degrees C. The compositions of the clear liquids and wet solid phases were analyzed by inductively coupled plasma atomic emission spectrometry (ICP-AES), and the results show that, as the Na2O concentration increases, the Al2O3 solubility initially increases monotonically, to maximum values of 100 w (mass fraction) = 33.58 and 35.86 at (150 and 180) degrees C, respectively, and then decreases. At both temperatures, the solid phases were determined to be Al2O3 center dot H2O, Na2O center dot Al2O3 center dot 2.5H(2)O, Na2O center dot Al2O3, and NaOH by X-ray diffraction coupled with Schreinemaker's method. The phase diagrams indicate that, as the temperature increases, the Na2O center dot Al2O3 center dot 2.5H(2)O phase region shrinks, while that of the Na2O center dot Al2O3 phase expands.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]ALKALINE-SOLUTIONS ; SODIUM ALUMINATE
收录类别SCI
原文出处://WOS:000279508100018
语种英语
WOS记录号WOS:000279508100018
公开日期2013-11-28
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/6426]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Jin, Wei,Zheng, Shili,Du, Hao,et al. Phase Diagrams for the Ternary Na2O-Al2O3-H2O System at (150 and 180) degrees C[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2010,55(7):2470-2473.
APA Jin, Wei,Zheng, Shili,Du, Hao,Xu, Hongbin,Wang, Shaona,&Zhang, Yi.(2010).Phase Diagrams for the Ternary Na2O-Al2O3-H2O System at (150 and 180) degrees C.JOURNAL OF CHEMICAL AND ENGINEERING DATA,55(7),2470-2473.
MLA Jin, Wei,et al."Phase Diagrams for the Ternary Na2O-Al2O3-H2O System at (150 and 180) degrees C".JOURNAL OF CHEMICAL AND ENGINEERING DATA 55.7(2010):2470-2473.

入库方式: OAI收割

来源:过程工程研究所

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