Preparation of CoOx/CeO2 Binary Oxides for NOx Storage and Reduction at Low Temperature
文献类型：期刊论文
| 作者 | Liu Hai-Di; Wei Lian-Qi; Yue Ren-Liang; Chen Yun-Fa |
| 刊名 | CHINESE JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 26期号:5页码:749-756 |
| 关键词 | NOx CeO2 CoOx adsorption reduction |
| ISSN号 | 1001-4861 |
| 其他题名 | Chin. J. Inorg. Chem. |
| 中文摘要 | The preparation of NOx storage and reduction catalyst using porous silica bead and active carbon as the support was studied. The optimized molar ratio of Co to Ce was obtained. The low temperature nitrogen adsorp-desorption was employed to measure the surface area and pore volume of the samples. The crystal structure of the metal element in the catalyst was investigated by XRD analysis. The results indicate that the best NOx adsorption performance is achieved when the n(Co)/n(Co)=75/25. When porous silica sphere is utilized as the support, the NOx is mainly adsorbed by the binary oxide composed of CoOx and CeO2; however, when the active carbon is used as the support, it makes obvious contribution in NOx adsorption, as a result, the NOx adsorption capacity of the sample is greatly increased. An adsorption mechanism upon NOx is also proposed and the NH3 reduction behavior of the sample was investigated. |
| 英文摘要 | The preparation of NOx storage and reduction catalyst using porous silica bead and active carbon as the support was studied. The optimized molar ratio of Co to Ce was obtained. The low temperature nitrogen adsorp-desorption was employed to measure the surface area and pore volume of the samples. The crystal structure of the metal element in the catalyst was investigated by XRD analysis. The results indicate that the best NOx adsorption performance is achieved when the n(Co)/n(Co)=75/25. When porous silica sphere is utilized as the support, the NOx is mainly adsorbed by the binary oxide composed of CoOx and CeO2; however, when the active carbon is used as the support, it makes obvious contribution in NOx adsorption, as a result, the NOx adsorption capacity of the sample is greatly increased. An adsorption mechanism upon NOx is also proposed and the NH3 reduction behavior of the sample was investigated. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CATALYSTS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000278131400003 |
| 公开日期 | 2013-11-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6447]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Multi Phase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Hai-Di,Wei Lian-Qi,Yue Ren-Liang,et al. Preparation of CoOx/CeO2 Binary Oxides for NOx Storage and Reduction at Low Temperature[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2010,26(5):749-756. |
| APA | Liu Hai-Di,Wei Lian-Qi,Yue Ren-Liang,&Chen Yun-Fa.(2010).Preparation of CoOx/CeO2 Binary Oxides for NOx Storage and Reduction at Low Temperature.CHINESE JOURNAL OF INORGANIC CHEMISTRY,26(5),749-756. |
| MLA | Liu Hai-Di,et al."Preparation of CoOx/CeO2 Binary Oxides for NOx Storage and Reduction at Low Temperature".CHINESE JOURNAL OF INORGANIC CHEMISTRY 26.5(2010):749-756. |
入库方式： OAI收割
来源：过程工程研究所
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