Shape-Controlled Synthesis of Cobalt-based Nanocubes, Nanodiscs, and Nanoflowers and Their Comparative Lithium-Storage Properties
文献类型:期刊论文
作者 | Chen, Jun Song2; Zhu, Ting2; Hu, Qiu Hong1; Gao, Junjie3; Su, Fabing3; Qiao, Shi Zhang1; Lou, Xiong Wen2 |
刊名 | ACS APPLIED MATERIALS & INTERFACES
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出版日期 | 2010-12-01 |
卷号 | 2期号:12页码:3628-3635 |
关键词 | cobalt-based nanocube nanodiscs nanoflower lithium-ion batteries |
ISSN号 | 1944-8244 |
其他题名 | ACS Appl. Mater. Interfaces |
中文摘要 | Facile hydrothermal methods have been developed to synthesize large Co(3)O(4) nanocubes, beta-Co(OH)(2) hexagonal nanodiscs and nanoflowers. Samples are thoroughly characterized by field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller method, and thermogravimetric analysis. The Co(3)O(4) nanocubes have an average size of about 350 nm with a perfect cubic shape, and the beta-Co(OH)(2) nanodiscs are uniform hexagonal platelets, whereas the beta-Co(OH)(2) nanoflowers are assembled from large sheetlike subunits, After thermal annealing in air at a moderate temperature, the as-prepared beta-Co(OH)(2) samples can be converted into spinel Co(3)O(4) without significant alterations in morphology. We have also Investigated the comparative lithium storage properties of these three Co(3)O(4) samples with distinct morphologies. The nanoflower sample shows highly reversible lithium storage capability after 100 charge-discharge cycles. |
英文摘要 | Facile hydrothermal methods have been developed to synthesize large Co(3)O(4) nanocubes, beta-Co(OH)(2) hexagonal nanodiscs and nanoflowers. Samples are thoroughly characterized by field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller method, and thermogravimetric analysis. The Co(3)O(4) nanocubes have an average size of about 350 nm with a perfect cubic shape, and the beta-Co(OH)(2) nanodiscs are uniform hexagonal platelets, whereas the beta-Co(OH)(2) nanoflowers are assembled from large sheetlike subunits, After thermal annealing in air at a moderate temperature, the as-prepared beta-Co(OH)(2) samples can be converted into spinel Co(3)O(4) without significant alterations in morphology. We have also Investigated the comparative lithium storage properties of these three Co(3)O(4) samples with distinct morphologies. The nanoflower sample shows highly reversible lithium storage capability after 100 charge-discharge cycles. |
WOS标题词 | Science & Technology ; Technology |
类目[WOS] | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
研究领域[WOS] | Science & Technology - Other Topics ; Materials Science |
关键词[WOS] | NEGATIVE-ELECTRODE MATERIALS ; FIELD-EMISSION PROPERTIES ; ION BATTERY ELECTRODES ; ONE-DIMENSIONAL ARRAYS ; CO3O4 NANOWIRE ARRAYS ; ELECTROCHEMICAL PERFORMANCE ; CONTROLLED GROWTH ; ANODE MATERIALS ; OXIDE ; HYDROXIDE |
收录类别 | SCI |
原文出处 | |
语种 | 英语 |
WOS记录号 | WOS:000285449300033 |
公开日期 | 2013-11-28 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/6477] ![]() |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Univ Queensland, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia 2.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore 3.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Jun Song,Zhu, Ting,Hu, Qiu Hong,et al. Shape-Controlled Synthesis of Cobalt-based Nanocubes, Nanodiscs, and Nanoflowers and Their Comparative Lithium-Storage Properties[J]. ACS APPLIED MATERIALS & INTERFACES,2010,2(12):3628-3635. |
APA | Chen, Jun Song.,Zhu, Ting.,Hu, Qiu Hong.,Gao, Junjie.,Su, Fabing.,...&Lou, Xiong Wen.(2010).Shape-Controlled Synthesis of Cobalt-based Nanocubes, Nanodiscs, and Nanoflowers and Their Comparative Lithium-Storage Properties.ACS APPLIED MATERIALS & INTERFACES,2(12),3628-3635. |
MLA | Chen, Jun Song,et al."Shape-Controlled Synthesis of Cobalt-based Nanocubes, Nanodiscs, and Nanoflowers and Their Comparative Lithium-Storage Properties".ACS APPLIED MATERIALS & INTERFACES 2.12(2010):3628-3635. |
入库方式: OAI收割
来源:过程工程研究所
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