Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum
文献类型:期刊论文
作者 | Wang, Fei1,2; Mao, Mei-Fen2; Wei, Guo-Zhu2; Gao, Yuan2; Ren, Fu-Cai2; Liu, Ji-Kai1 |
刊名 | PHYTOCHEMISTRY
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出版日期 | 2013-11-01 |
卷号 | 95页码:428-435 |
关键词 | Daphniphyllum longeracemosum Daphniphyllaceae C-22 nor-Daphniphyllum alkaloid Alkaloid and iridoid hybrid Hybridaphniphylline Diels-Alder cycloaddition |
ISSN号 | 0031-9422 |
通讯作者 | Wang,F (reprint author),Chinese Acad Sci,State Key Lab Phytochem & Plant Resources West Ch,Kunming Inst Bot,Kunming 650201,Peoples R China.,wangfei@mail.kib.ac.cn ; jkliu@mail.kib.ac.cn |
英文摘要 | Two Daphniphyllum alkaloid and iridoid hybrids with the hitherto unknown decacyclic fused skeletons, hybridaphniphyllines A and B, along with one diamino Daphniphyllum alkaloid, daphnicyclidin I, were isolated from dried stems and leaves of Daphniphyllum longeracemosum. Their structures were elucidated on the basis of extensive spectroscopic analysis, and the absolute configuration of daphnicyclidin I was deduced by the CD exciton chirality method. A biogenetic pathway for 1 and 2 involving natural Diels-Alder cycloaddition is proposed. (C) 2013 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Life Sciences & Biomedicine |
学科主题 | Biochemistry & Molecular Biology ; Plant Sciences |
类目[WOS] | Biochemistry & Molecular Biology ; Plant Sciences |
研究领域[WOS] | Biochemistry & Molecular Biology ; Plant Sciences |
关键词[WOS] | PENTACYCLIC ALKALOIDS ; PAXIANUM ; BIOSYNTHESIS ; YUNNANENSE ; LACTONES ; HUMILE |
收录类别 | SCI ; IC |
资助信息 | Large-scale Compound Library project of National Development and Reform Commission of China;National Basic Research Program of China (973 Program) [2009CB522300];"Western Light" talents training program of Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000326901500040 |
公开日期 | 2014-01-13 |
源URL | [http://ir.kib.ac.cn/handle/151853/17409] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China 2.BioBioPha Co Ltd, Kunming 650201, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Fei,Mao, Mei-Fen,Wei, Guo-Zhu,et al. Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum[J]. PHYTOCHEMISTRY,2013,95:428-435. |
APA | Wang, Fei,Mao, Mei-Fen,Wei, Guo-Zhu,Gao, Yuan,Ren, Fu-Cai,&Liu, Ji-Kai.(2013).Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum.PHYTOCHEMISTRY,95,428-435. |
MLA | Wang, Fei,et al."Hybridaphniphyllines A and B, Daphniphyllum alkaloid and iridoid hybrids suggestive of Diels-Alder cycloaddition in Daphniphyllum longeracemosum".PHYTOCHEMISTRY 95(2013):428-435. |
入库方式: OAI收割
来源:昆明植物研究所
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