Gluconic acid aqueous solution: a task-specific bio-based solvent for ring-opening reactions of dihydropyrans
文献类型：期刊论文
| 作者 | Yang J(杨杰)1; Zhou BH(周炳华)1; Li MH(李明浩)1; Gu YL(顾彦龙)1,2 |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2013 |
| 卷号 | 69期号:3页码:1057-1064 |
| 关键词 | Green solvent Gluconic acid aqueous solution Ring-opening reaction Dihydropyran |
| ISSN号 | 0040-4020 |
| 通讯作者 | 顾彦龙 |
| 英文摘要 | Gluconic acid aqueous solution (GAAS) that is a largely available bio-based chemical was proved to be an effective task-specific medium for ring-opening reactions of dihydropyrans. In the presence of nucleophiles, such as indoles, 1,3-cyclohexanediones, N,N-dimethylaniline, N-methylaniline, 2-naphthol, and resorcin, a series of 2-substituted 1, 3-dicarbonyl compounds were synthesized in good to excellent yields. The first example of ring-opening of oxa-PicteteSpengler product with nucleophiles was also described. These results not only demonstrate the feasibility of using GAAS as a sustainable solvent, but also offer an effective way for the ring-opening reactions of dihydropyrans with nucleophiles. Because these reactions proceeded with excellent atom-economy in a sustainable bio-based solvent, the present method was thus characterized by many properties of green chemistry, such as green solvent, atomeconomy, and utilization of bio-based chemicals. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China (20903042;21173089);Specialized Research Fund for the Doctoral Program of Higher Education (20090142120081);The Program for new Century Excellent Talents in the University of China (NCET-10-0383);Chutian Scholar Program of the Hubei Provincial Government;the Fundamental Research Funds for the Central Universities (2011TS023) |
| 语种 | 英语 |
| WOS记录号 | WOS:000315060600009 |
| 公开日期 | 2013-12-30 |
| 源URL | [http://210.77.64.217/handle/362003/4946]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Inst Phys Chem & Ind Catalysis, Hubei Key Lab Mat Chem & Serv Failure, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China 2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang J,Zhou BH,Li MH,et al. Gluconic acid aqueous solution: a task-specific bio-based solvent for ring-opening reactions of dihydropyrans[J]. Tetrahedron,2013,69(3):1057-1064. |
| APA | Yang J,Zhou BH,Li MH,&Gu YL.(2013).Gluconic acid aqueous solution: a task-specific bio-based solvent for ring-opening reactions of dihydropyrans.Tetrahedron,69(3),1057-1064. |
| MLA | Yang J,et al."Gluconic acid aqueous solution: a task-specific bio-based solvent for ring-opening reactions of dihydropyrans".Tetrahedron 69.3(2013):1057-1064. |
入库方式： OAI收割
来源：兰州化学物理研究所
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