One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2
文献类型：期刊论文
| 作者 | Bai RX(白荣献)1; Zhang, Hongkun1; Mei FM(梅付名)1; Wang S(王庶)1; Li T(李涛)1; Gu YL(顾彦龙)1,2; Li GX(李光兴)1 |
| 刊名 | Green Chem.
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:10页码:2929-2934 |
| ISSN号 | 1463-9262 |
| 通讯作者 | 顾彦龙 ; 李光兴 |
| 英文摘要 | The one-pot synthesis of glycidol from glycerol and dimethyl carbonate (DMC) was developed by using a solid base catalyst. A series of solid base catalysts have been investigated in this reaction. It was found that NaAlO2, a cheap and easily available raw material, was a highly efficient heterogeneous catalyst for the one-pot synthesis of glycidol, and it can be easily recovered and reused. Under the reaction conditions of a DMC–glycerol molar ratio of 2, catalyst–glycerol weight ratio of 3%, reaction time of 90 min, and temperature of 80–92 °C, the conversion of glycerol and the selectivity to glycidol reached 94.7% and 80.7%, respectively. Activity tests of the catalyst after exposure to the air showed that, to a certain extent, the NaAlO2 catalyst is tolerant to water and carbon dioxide, which makes the present system a practically interesting process for glycidol synthesis. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China (21173089);Chutian Scholar Program of the Hubei provincial government;the Cooperative Innovation Center of Catalysts Materials of Hubei Province |
| 语种 | 英语 |
| WOS记录号 | WOS:000325593600038 |
| 公开日期 | 2013-12-30 |
| 源URL | [http://210.77.64.217/handle/362003/4947]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Large Format Battery Mat & Syst, Minist Educ,Sch Chem & Chem Engn, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bai RX,Zhang, Hongkun,Mei FM,et al. One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2[J]. Green Chem.,2013,15(10):2929-2934. |
| APA | Bai RX.,Zhang, Hongkun.,Mei FM.,Wang S.,Li T.,...&Li GX.(2013).One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2.Green Chem.,15(10),2929-2934. |
| MLA | Bai RX,et al."One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2".Green Chem. 15.10(2013):2929-2934. |
入库方式： OAI收割
来源：兰州化学物理研究所
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