N‑Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitroso- benzenes: A Highly Regioselective Umpolung Strategy
文献类型：期刊论文
| 作者 | Renfeng Han; Qi J(齐静); Jixiang Gu; Ma DH(马东辉); Xie XG(谢新刚); She XG(厍学功) |
| 刊名 | ACS Catalysis
 |
| 出版日期 | 2013 |
| 卷号 | 3页码:2705-2709 |
| 关键词 | N-heterocyclic carbene [3+2] annulation regioselective umpolung alkynyl aldehydes nitrosobenzenes |
| ISSN号 | 2155-5435 |
| 通讯作者 | 厍学功 |
| 英文摘要 | N-Heterocyclic carbene-catalyzed formal [3+2] annulation of alkynyl aldehydes and nitrosobenzenes has been reported. This transformation provided the novel C−X bond formation under mild conditions in moderate to satisfactory yields. The catalytic protocol allows for a rapid construction of 2,5-disubstituted isoxazol-3(2H)-ones and 2,3-disubstituted isoxazol-5(2H)-ones from the same materials via a highly regioselectively umpolung stratgy. |
| 收录类别 | SCI |
| 资助信息 | the NSFC (21125207;21102062;21072086);the MOST (2010CB833203);PCSIRT (IRT1138);the FRFCU (lzujbky-2013-49;lzujbky-2013-ct02);Program 111 |
| 语种 | 英语 |
| 公开日期 | 2014-01-06 |
| 源URL | [http://210.77.64.217/handle/362003/4972]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Renfeng Han,Qi J,Jixiang Gu,et al. N‑Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitroso- benzenes: A Highly Regioselective Umpolung Strategy[J]. ACS Catalysis,2013,3:2705-2709. |
| APA | Renfeng Han,Qi J,Jixiang Gu,Ma DH,Xie XG,&She XG.(2013).N‑Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitroso- benzenes: A Highly Regioselective Umpolung Strategy.ACS Catalysis,3,2705-2709. |
| MLA | Renfeng Han,et al."N‑Heterocyclic Carbene-Catalyzed Formal [3+2] Annulation of Alkynyl Aldehydes with Nitroso- benzenes: A Highly Regioselective Umpolung Strategy".ACS Catalysis 3(2013):2705-2709. |
入库方式： OAI收割
来源：兰州化学物理研究所
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