Asymmetric Total Synthesis of Fusarentin 6-Methyl Ether and Its Biomimetic Transformation into Fusarentin 6,7-Dimethyl Ether, 7-O-Demethylmonocerin, and (+)-Monocerin
文献类型：期刊论文
| 作者 | Fang WB(方文博)1; Xie XG(谢新刚)1; Zhao CG(赵常贵)1; Jing P(靖鹏)1; Li HL(李辉林)1; Wang, Zhengshen1; Gu, Jixiang1; She XG(厍学功)1,2 |
| 刊名 | Journal of Organic Chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 78期号:12页码:6338-6343 |
| ISSN号 | 0022-3263 |
| 通讯作者 | 厍学功 |
| 英文摘要 | A concise asymmetric total synthesis of a fiisarentin ether (1) with sequential biomimetic transformation to its analogues fusarentin 6,7-dimethyl ether (2), 7-O-demethylmonocerin (3), and (+)-monocerin (4) has been accomplished. The cis-fused furobenzopyranones of 7-O-demethylmonocerin (3) and (+)-monocerin (4) were efficiently constructed via an intramolecular nucleophilic trapping of a quinonemethide intermediate, which was obtained by benzylic oxidation of fusarentin 6-methyl ether (1) using hypeivalent iodine reagent. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the NSFC (21125207;21102062;21072086);the MOST (2010CB833203);PCSIRT (IRT1138);the FRFCU (lzujbky-2013-49;lzujbky-2013-ct02);Program 111 |
| 语种 | 英语 |
| WOS记录号 | WOS:000320979500056 |
| 公开日期 | 2014-01-06 |
| 源URL | [http://210.77.64.217/handle/362003/4977]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang WB,Xie XG,Zhao CG,et al. Asymmetric Total Synthesis of Fusarentin 6-Methyl Ether and Its Biomimetic Transformation into Fusarentin 6,7-Dimethyl Ether, 7-O-Demethylmonocerin, and (+)-Monocerin[J]. Journal of Organic Chemistry,2013,78(12):6338-6343. |
| APA | Fang WB.,Xie XG.,Zhao CG.,Jing P.,Li HL.,...&She XG.(2013).Asymmetric Total Synthesis of Fusarentin 6-Methyl Ether and Its Biomimetic Transformation into Fusarentin 6,7-Dimethyl Ether, 7-O-Demethylmonocerin, and (+)-Monocerin.Journal of Organic Chemistry,78(12),6338-6343. |
| MLA | Fang WB,et al."Asymmetric Total Synthesis of Fusarentin 6-Methyl Ether and Its Biomimetic Transformation into Fusarentin 6,7-Dimethyl Ether, 7-O-Demethylmonocerin, and (+)-Monocerin".Journal of Organic Chemistry 78.12(2013):6338-6343. |
入库方式： OAI收割
来源：兰州化学物理研究所
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