(K1-xNax)(2)Al2B2O7 with 0 <= x < 0.6: A promising nonlinear optical crystal
文献类型：期刊论文
| 作者 | He, M ; Chen, XL ; Okudera, H ; Simon, A |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 2005 |
| 卷号 | 17期号:8页码:2193 |
| 关键词 | K2AL2B2O7 CRYSTAL GROWTH GENERATION BORATE KAB |
| ISSN号 | 0897-4756 |
| 通讯作者 | He, M: Max Planck Inst Solid State Res, Heisenbergstr 1, D-70569 Stuttgart, Germany. |
| 中文摘要 | Up to about 60% K+ in K2Al2B2O7 (KABO), a well-known nonlinear optical material, can be substituted by Na+ with the structure type being retained. AlO4 tetrahedra and BO3 triangles in the Na-substituted compound tilt to adjust to the local distribution of alkali-metal atoms, which explains the large range of homogeneity. When the Na+ substitution is higher than 50%, the decomposition and volatility of KABO are strongly inhibited and the sample melts congruently at about 940 degrees C, which makes it possible to grow bulk crystals from the melt directly. The second harmonic generation property of KNaAl2B2O7 is close to that of KABO. Taking the crystal growth into account, (K1-xNax)(2)Al2B2O7 (0 <= X < 0.6) seems to be a more promising nonlinear optical material than KABO. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/32567]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | He, M,Chen, XL,Okudera, H,et al. (K1-xNax)(2)Al2B2O7 with 0 <= x < 0.6: A promising nonlinear optical crystal[J]. CHEMISTRY OF MATERIALS,2005,17(8):2193. |
| APA | He, M,Chen, XL,Okudera, H,&Simon, A.(2005).(K1-xNax)(2)Al2B2O7 with 0 <= x < 0.6: A promising nonlinear optical crystal.CHEMISTRY OF MATERIALS,17(8),2193. |
| MLA | He, M,et al."(K1-xNax)(2)Al2B2O7 with 0 <= x < 0.6: A promising nonlinear optical crystal".CHEMISTRY OF MATERIALS 17.8(2005):2193. |
入库方式： OAI收割
来源：物理研究所
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