A Novel Application of Plasmonics: Plasmon-Driven Surface-Catalyzed Reactions
文献类型：期刊论文
| 作者 | Sun, MT ; Xu, HX |
| 刊名 | SMALL
 |
| 出版日期 | 2012 |
| 卷号 | 8期号:18页码:2777 |
| 关键词 | ENHANCED RAMAN-SCATTERING CHARGE-TRANSFER P-AMINOTHIOPHENOL AG NANOPARTICLES INDUCED PHOTOREDUCTION INDUCED PHOTOREACTION SILVER NANOPARTICLES METAL NANOSTRUCTURES GOLD NANOPARTICLES CHEMICAL MECHANISM |
| ISSN号 | 1613-6810 |
| 通讯作者 | Sun, MT: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, POB 603-146, Beijing 100190, Peoples R China. |
| 中文摘要 | The first experimental and theoretical evidence of the surface-catalyzed reaction of p,p'-dimercaptoazobenzene (DMAB) produced from para-aminothiophenol (PATP) by local surface plasmons was reported in 2010, and since that time a series of investigations have supported these findings using different experimental and theoretical methods. Recent work has also found that local plasmons can drive a surface-catalyzed reaction of DMAB converted from 4-nitrobenzenethiol (4NBT), assisted by local surface plasmons. There are at least three important discoveries in these investigations: 1) in the field of surface-enhanced Raman scattering (SERS) the widely accepted misinterpretation (since 1994) that the chemical mechanism resulting in three additional Raman peaks of PATP in Ag or Au solutions has been corrected with a new mechanism; 2) it is confirmed that SERS is not always a noninvasive technique, and under certain conditions cannot always obtain the vibrational fingerprint information of the original surface species; 3) a novel method to synthesize new molecules, induced by local surface plasmons or plasmon waveguides on the nanoscale, has been found. This Review considers recent novel applications of plasmonics to chemical reactions, especially to plasmon-driven surface-catalyzed reactions. |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [90923003, 10874234, 20703064]; National Basic Research Project of China [2009CB930701] |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/33122]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun, MT,Xu, HX. A Novel Application of Plasmonics: Plasmon-Driven Surface-Catalyzed Reactions[J]. SMALL,2012,8(18):2777. |
| APA | Sun, MT,&Xu, HX.(2012).A Novel Application of Plasmonics: Plasmon-Driven Surface-Catalyzed Reactions.SMALL,8(18),2777. |
| MLA | Sun, MT,et al."A Novel Application of Plasmonics: Plasmon-Driven Surface-Catalyzed Reactions".SMALL 8.18(2012):2777. |
入库方式： OAI收割
来源：物理研究所
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