A preliminary study on a new LiBOB/acetamide solid phase transition electrolyte
文献类型：期刊论文
| 作者 | Xie, B ; Li, LF ; Li, H ; Chen, LQ |
| 刊名 | SOLID STATE IONICS
 |
| 出版日期 | 2009 |
| 卷号 | 180期号:9-10页码:688 |
| 关键词 | TEMPERATURE MOLTEN-SALT LICF3SO3/ACETAMIDE COMPLEX SYSTEM DOUBLE-LAYER CAPACITORS LITHIUM-ION BATTERIES ELECTROCHEMICAL PROPERTIES LIQUID FORMATION LITFSI ACETAMIDE CONDUCTIVITY LIBOB |
| ISSN号 | 0167-2738 |
| 通讯作者 | Li, H: Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China. |
| 中文摘要 | New solid electrolytes containing acetamide and lithium bioxalato borate (LiBOB) with different molar ratios have been investigated. Their melting points (T(m)) are around 42 degrees C. The ionic conductivities and activation energies vary drastically below and above T(m). indicating a typical feature of phase transition electrolyte. The ionic conductivity of the LiBOB/acetamide electrolyte with a molar ratio of 1:8 is 5 x 10(-8) S cm(-1) at 25 degrees C but increases to 4 x 10(-3) S cm(-1) at 60 degrees C. It was found that anode materials, such as graphite and Li(4)Ti(5)O(12), could not discharge and charge properly in this electrolyte at 60 degrees C due to the difficulty in forming a stable passivating layer on the anodes. However, a Li/LiFePO(4) Cell with this electrolyte can be charged properly after heating to 60 degrees C, but cannot be charged at room temperature. Although the LiBOB/acetamide electrolytes are not suitable for Li-ion batteries due to poor electrode compatibility, the current results indicate that a solid electrolyte with a slightly higher phase transition temperature than room temperature may find potential application in stationary battery for energy storage where the electrolyte is at high conductive liquid state at elevated temperature and low conductive Solid state at low temperature. The interaction between acetamide and LiBOB in the electrolyte is also studied by Raman and FTIR spectroscopy. (c) 2009 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 资助信息 | NSFC [50672122, 50730005]; "863" project [2006AA03Z346, 2006AA03Z228]; "973" Project [2007CB936501] |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/33182]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xie, B,Li, LF,Li, H,et al. A preliminary study on a new LiBOB/acetamide solid phase transition electrolyte[J]. SOLID STATE IONICS,2009,180(9-10):688. |
| APA | Xie, B,Li, LF,Li, H,&Chen, LQ.(2009).A preliminary study on a new LiBOB/acetamide solid phase transition electrolyte.SOLID STATE IONICS,180(9-10),688. |
| MLA | Xie, B,et al."A preliminary study on a new LiBOB/acetamide solid phase transition electrolyte".SOLID STATE IONICS 180.9-10(2009):688. |
入库方式： OAI收割
来源：物理研究所
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