A vibrational spectroscopic study on the interaction between lithium salt and ethylene carbonate plasticizer for PAN-based electrolytes
文献类型：期刊论文
| 作者 | Wang, ZX ; Huang, BY ; Huang, H ; Xue, RJ ; Chen, LQ ; Wang, FO |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 1996 |
| 卷号 | 143期号:5页码:1510 |
| 关键词 | RAMAN TEMPERATURE LICLO4 |
| ISSN号 | 0013-4651 |
| 通讯作者 | Wang, ZX: CHINESE ACAD SCI,INST PHYS,LAB SOLID STATE ION,BEIJING 100080,PEOPLES R CHINA. |
| 中文摘要 | The Raman and infrared (IR) spectra of ethylene carbonate (EC) containing various concentrations of lithium perchlorate have been studied. It was found that both the vibrational frequencies and the relative intensities of the bands related to the ring structure and C=O group of the EC molecule change with the concentration of LiClO4 in the solution. The results indicate that there are rather strong interactions between Li+ ions and EC molecules. The interactions between the Li+ ions and EC molecules occur on all three oxygen atoms of the carbonate group. Another result given by Raman and IR spectroscopy is that the vibrational modes of ClO4- anions at 460 and at 624 cm(-1) are nearly as sensitive as the previously reported ClO4- bands at 930 cm(-1) in detecting ion aggregates in the LiClO4/EC solutions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/33345]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, ZX,Huang, BY,Huang, H,et al. A vibrational spectroscopic study on the interaction between lithium salt and ethylene carbonate plasticizer for PAN-based electrolytes[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,1996,143(5):1510. |
| APA | Wang, ZX,Huang, BY,Huang, H,Xue, RJ,Chen, LQ,&Wang, FO.(1996).A vibrational spectroscopic study on the interaction between lithium salt and ethylene carbonate plasticizer for PAN-based electrolytes.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,143(5),1510. |
| MLA | Wang, ZX,et al."A vibrational spectroscopic study on the interaction between lithium salt and ethylene carbonate plasticizer for PAN-based electrolytes".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 143.5(1996):1510. |
入库方式： OAI收割
来源：物理研究所
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