Adjustment and control of SERS activity of metal substrates by pressure
文献类型：期刊论文
| 作者 | Xia, LX ; Jia, Y ; Liu, GY ; Yang, ZL ; Chen, XW ; Zhang, HL ; Sun, MT |
| 刊名 | JOURNAL OF RAMAN SPECTROSCOPY
 |
| 出版日期 | 2010 |
| 卷号 | 41期号:4页码:398 |
| 关键词 | ENHANCED RAMAN-SCATTERING SURFACE-PLASMON RESONANCE SILVER ELECTRODE CHEMICAL MECHANISM AU NANOPARTICLES PHOTON-EMISSION SPECTROSCOPY SPECTRA FILMS AG |
| ISSN号 | 0377-0486 |
| 通讯作者 | Xia, LX: Liaoning Univ, Coll Chem, 66 Chongshan Middle Rd, Shenyang 110036, Peoples R China. |
| 中文摘要 | Metal pellets of silver and copper for surface-enhanced Raman scattering (SERS) spectroscopy were prepared by compression with different pressures. It was found that the SERS activity of the pellet could be controlled by pressure. Enhanced Raman scattering properties of the metal pellets in the presence of adsorbed 4-mercaptobenzoic acid (4-MBA) with excitation at 632.8 or 514 nm could be obtained by choosing proper pressure of pellatization. The SERS peak intensity of the band at similar to 1584 cm(-1) of 4-MBA adsorbed on the metal pellets varies as a function of applied pressure, and which is about 1.2-32 times greater than when it is adsorbed on silver and copper particles. The calculated results of three-dimensional finite-difference time-domain method (3D-FDTD) are in good agreement with the experimental data. Moreover, no spurious peaks appear in the SERS spectra of the samples because no other chemicals are involved in the simple preparation process of the metal pellets, which will facilitate its use as an SERS-active substrate for analytical purposes. In summary, SERS-active metal pellets can be produced simply and cost effectively by the method reported here, and this method is expected to be utilized in the development of SERS-based analytical devices. Copyright (C) 2009 John Wiley & Sons, Ltd. |
| 收录类别 | SCI |
| 资助信息 | Shenyang Natural Science Foundation, China [071483, 2008gx-011]; Natural Science Foundation of China [20703064, 10874234]; National Basic Research Project of China [2009CB930701, 2007CB936804] |
| 语种 | 英语 |
| 公开日期 | 2013-09-17 |
| 源URL | [http://ir.iphy.ac.cn/handle/311004/33490]  |
| 专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xia, LX,Jia, Y,Liu, GY,et al. Adjustment and control of SERS activity of metal substrates by pressure[J]. JOURNAL OF RAMAN SPECTROSCOPY,2010,41(4):398. |
| APA | Xia, LX.,Jia, Y.,Liu, GY.,Yang, ZL.,Chen, XW.,...&Sun, MT.(2010).Adjustment and control of SERS activity of metal substrates by pressure.JOURNAL OF RAMAN SPECTROSCOPY,41(4),398. |
| MLA | Xia, LX,et al."Adjustment and control of SERS activity of metal substrates by pressure".JOURNAL OF RAMAN SPECTROSCOPY 41.4(2010):398. |
入库方式： OAI收割
来源：物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。