Characterization of interactions among 3-hydroxypropionitrile/LiI electrolytes
文献类型:期刊论文
作者 | Wang, HX ; Xue, BF ; Hu, YS ; Wang, ZX ; Meng, QB ; Huang, XJ ; Chen, LQ |
刊名 | ELECTROCHEMICAL AND SOLID STATE LETTERS
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出版日期 | 2004 |
卷号 | 7期号:10页码:A302 |
关键词 | LITHIUM ION SOLAR-CELL CONVERSION ALCOHOLS SPECTRA LIGANDS SALTS BR CL |
ISSN号 | 1099-0062 |
通讯作者 | Wang, HX: Chinese Acad Sci, Inst Phys, State Key Lab Surface Phys, POB 603, Beijing 100080, Peoples R China. |
中文摘要 | Solid electrolyte-based on lithium iodide (LiI) and 3-hydroxypropionitrile (HPN) for dye-sensitized solar cells (DSSCs) has been synthesized. Fourier transform infrared, ac impedance spectroscopy, and differential scanning calorimetry are employed to characterize the properties of the composite. Its conductivity increases with decreasing LiI content. Maximum conductivity of 3.1 x 10(-3) S cm(-1) is obtained at LiI/HPN = 1: 4 (molar ratio) at room temperature. Comparison on the interactions of the Li+ ions with the hydroxyl and with the nitrile groups indicates that Li+-nitrile coordination is preferential. A light-to-electricity conversion efficiency of 1.8% at AM 1.5 illumination has been obtained on a DSSC employing this electrolyte. (C) 2004 The Electrochemical Society. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-17 |
源URL | [http://ir.iphy.ac.cn/handle/311004/34638] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Wang, HX,Xue, BF,Hu, YS,et al. Characterization of interactions among 3-hydroxypropionitrile/LiI electrolytes[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS,2004,7(10):A302. |
APA | Wang, HX.,Xue, BF.,Hu, YS.,Wang, ZX.,Meng, QB.,...&Chen, LQ.(2004).Characterization of interactions among 3-hydroxypropionitrile/LiI electrolytes.ELECTROCHEMICAL AND SOLID STATE LETTERS,7(10),A302. |
MLA | Wang, HX,et al."Characterization of interactions among 3-hydroxypropionitrile/LiI electrolytes".ELECTROCHEMICAL AND SOLID STATE LETTERS 7.10(2004):A302. |
入库方式: OAI收割
来源:物理研究所
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